广州化学2026，Vol.51Issue(3)：76-81,6.DOI:10.16560/j.cnki.gzhx.20252723
以硅氧烷为主体的环氧基聚硅氧烷的合成及应用进展
Siloxane-Based Epoxy-Functionalized Polysiloxanes:A Review of Synthesis and Applications
仇丹 1潘天予 1徐天翼 1袁媛 1黄月文 2王斌3
作者信息
- 1. 中国科学院广州化学研究所,广东 广州 510650||中国科学院大学,北京 100049
- 2. 中国科学院广州化学研究所,广东 广州 510650||中国科学院新型特种精细化学品工程实验室,广东 广州 510650||国科广化韶关新材料研究院,广东 韶关 512400
- 3. 中国科学院广州化学研究所,广东 广州 510650||国科广化韶关新材料研究院,广东 韶关 512400
- 折叠
摘要
Abstract
Building upon existing reviews of epoxy-modified silicones,this review systematically delineates the synthetic pathways,molecular structure classifications,and multifunctional application mechanisms of epoxy-functionalized polysiloxanes from the perspective of molecular design,with a specific focus on architectures where the siloxane chain serves as the backbone.It begins with a concise introduction to epoxy-functionalized polysiloxanes as functional polymers that combine the advantages of both silicones and epoxy resins.The review then provides a detailed overview of the characteristics and control strategies of four principal synthetic methods,offering a systematic classification of these molecules based on their stereo-structure and epoxy group types.Particular emphasis is placed on summarizing their application mechanisms as adhesion promoters,toughening agents,and reinforcing modifiers in enhancing material adhesion,low-temperature toughness,and mechanical strength.The synergistic enhancement effects achieved through compositing with heteroatoms and nanomaterials are also discussed.Finally,future research directions are prospected,focusing on the molecular design of phenyl-backbone structures,multifunctional integration,and green sustainable pathways.关键词
环氧基聚硅氧烷/立体结构/合成方法/相容性/相分离/功能应用Key words
epoxy-functionalized polysiloxane/stereo structure/synthetic methods/compatibility/phase separation/functional application分类
化学化工引用本文复制引用
仇丹,潘天予,徐天翼,袁媛,黄月文,王斌..以硅氧烷为主体的环氧基聚硅氧烷的合成及应用进展[J].广州化学,2026,51(3):76-81,6.
