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MH/LLDPE复合材料的制备与性能研究

谢平 何奕汛 刘述梅 林绍泽 汤家俊 刘羽玲 刘显勇 王忠强 杨佳茜

合成材料老化与应用2026,Vol.55Issue(3):24-28,23,6.
合成材料老化与应用2026,Vol.55Issue(3):24-28,23,6.

MH/LLDPE复合材料的制备与性能研究

Fabrication and Performance Study of MH/LLDPE Composite Materials

谢平 1何奕汛 2刘述梅 2林绍泽 3汤家俊 3刘羽玲 3刘显勇 3王忠强 3杨佳茜4

作者信息

  • 1. 深圳市中塑新材料有限公司,广东 深圳 518000||广东中塑新材料股份有限公司,广东东莞 523860
  • 2. 华南理工大学,广东 广州 510641
  • 3. 广东中塑新材料股份有限公司,广东东莞 523860
  • 4. 太原科技大学,山西太原 030024
  • 折叠

摘要

Abstract

Magnesium hydroxide(MH)/linear low-density polyethylene(LLDPE)composites exhibit drawbacks such as low flame retardant efficiency and poor compatibility,which subsequently lead to reduced processing fluidity and diminished mechanical properties.Moreover,in high-fill-concentration MH/LLDPE composite systems(60 wt%MH),traditional processing additives struggle to achieve the dual objectives of excellent flame retardancy and mechanical performance.To address these challenges,this study adopts a synergistic modification strategy combining three self-developed small-molecule flow modifiers(LC-M,LC-F,and NLC-2F)with commercial polyethylene wax(PEW),specifically targeting high-filled MH/LLDPE systems.The mechanism of LC-F in the composite system was thoroughly investigated using multi dimensional methods including apparent property testing,micromorphology characterization,and mechanical property testing.The results demonstrate that LC-F significantly reduces the agglomeration of MH particles.During melt blending,LC-F effectively decreases frictional resistance interparticles and between MH particles and the LLDPE matrix.In the deformation process,LC-F in the composite can promote the participation of MH particles in deformation,thereby significantly improving the toughness of the composite.In addition,the introduction of LC-F also significantly enhances the flame retardant properties of the composite,with its limiting oxygen index(LOI)increasing from 29.8%to 33.1%.

关键词

高填充/复合材料/含氟小分子液晶/液晶性/线性低密度聚乙烯/流动改性剂

Key words

high filler loading/composite materials/fluorinated small-molecule liquid crystals/liquid crystallinity/linear low-density polyethylene/flow modifier

分类

化学化工

引用本文复制引用

谢平,何奕汛,刘述梅,林绍泽,汤家俊,刘羽玲,刘显勇,王忠强,杨佳茜..MH/LLDPE复合材料的制备与性能研究[J].合成材料老化与应用,2026,55(3):24-28,23,6.

基金项目

东莞市重大科技项目库入库项目(项目编号:303163825026、401190606015). (项目编号:303163825026、401190606015)

合成材料老化与应用

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