化工学报2026，Vol.77Issue(5)：2338-2358,21.DOI:10.11949/0438-1157.20251084
硫基光催化剂在高效光催化制氢中研究进展
Recent advances and perspectives on sulfide-based photocatalysts for hydrogen production
摘要
Abstract
The accelerated industrialization has intensified global concerns over energy consumption and carbon emissions.Hydrogen energy,characterized by water-only combustion products,abundant availability,and high calorific value,constitutes a pivotal element in future energy systems.Photocatalytic water splitting represents a promising strategy for clean hydrogen production;however,its efficiency and practicality are limited by the constrained utilization of visible light and rapid recombination of photogenerated charges photocatalytic water splitting for hydrogen production is a highly promising hydrogen energy production technology,but its efficiency and practicality are limited by factors such as low visible light utilization and rapid recombination of photogenerated charge carriers.Sulfide-based catalysts leverage the advantages of sulfur doping to modify band structures,broadening the light response range,enhancing stability,and suppressing charge recombination.This review synthesizes recent advances in sulfide-based photocatalysts for hydrogen evolution,focusing on characteristic properties and modification approaches for representative systems including CdS,In2S3,ZnS,ZnIn2S4,and CdZnS.Performance enhancements are achieved through morphology engineering,elemental doping,and cocatalyst integration.Through the design of sulfur vacancies,the cyclic regeneration of sulfide-based materials is achieved,reducing reliance on precious metals,which aligns with the sustainability requirements for renewable materials.Collectively,this work establishes fundamental principles for developing efficient,stable photocatalytic systems,paving the way toward sustainable energy infrastructure transformation.关键词
光催化制氢/硫基光催化剂/催化剂优化/异质结/助催化剂Key words
photocatalytic hydrogen production/sulfur-based photocatalyst/catalyst optimization/heterojunctions/co-catalyst分类
化学化工引用本文复制引用
张晨阳,顾春鹏,韩长存..硫基光催化剂在高效光催化制氢中研究进展[J].化工学报,2026,77(5):2338-2358,21.基金项目
国家自然科学基金项目(52103339) （52103339）
