石油与天然气化工2026，Vol.55Issue(3)：60-67,8.DOI:10.3969/j.issn.1007-3426.2026.03.007
烟气凝液中Fe3+、Cl-、NO3-对S31254钢腐蚀行为的影响
The influence of Fe3+,Cl-and NO3-on the corrosion behavior of S31254 steel in flue gas condensate
摘要
Abstract
Objective To address the corrosion failure of exhaust gas treatment equipment in high-temperature acidic flue gas environments,this study aims to reveal the corrosion mechanisms of three corrosive ions,Fe3+,Cl-,and NO-3,in simulated flue gas condensate on S31254 steel,thereby providing technical support for engineering applications.Method Fe3+(at mass concentrations of 50,200,and 2 000 mg/L),Cl-(mass concentration 200 mg/L),and NO-3(mass concentration 200 mg/L),were prepared.High-temperature immersion tests were conducted,and the morphology,composition,and elemental distribution of the corrosion products were systematically analyzed using scanning electron microscope,X-ray diffraction dnalysis,and energy dispersive spectrometer,with a focus on the effects of different ions on the corrosion behavior of the material.Result The results indicate that Fe3+,Cl-,and NO-3all significantly promote the corrosion of S31254 austenitic stainless steel.Among them,Fe3+at a low mass concentration(50 mg/L),results in weight gain of the specimen,while at a high concentration(2 000 mg/L),it intensifies corrosion,forming a continuous and thick corrosion product film.XRD analysis reveals the presence of Fe2O2CO3 on the specimen surface.The presence of Cl-increases the thickness of the corrosion product film and leads to the highest corrosion rate.In contrast,NO-3 promotes the formation of a thin but porous corrosion product film and induces pitting corrosion.EDS analysis shows significant loss of Fe and Ni,while Cr and Mo are enriched on the specimen surface.Conclusion This study elucidates the influence of corrosive ions in the high-temperature acidic flue gas condensation environment.The findings provide a scientific basis for material selection,corrosion protection,and operation management of tail gas treatment equipment in natural gas purification plants,and also serve as a reference for subsequent related research.关键词
烟气凝液/S31254钢/腐蚀/温度/产物膜/元素分布Key words
flue gas condensate/S31254 steel/corrosion/temperature/product film/elemental distribution引用本文复制引用
江晶晶,叶海木,宋莉芳..烟气凝液中Fe3+、Cl-、NO3-对S31254钢腐蚀行为的影响[J].石油与天然气化工,2026,55(3):60-67,8.基金项目
中国石油西南油气田公司科技项目"净化厂硫黄回收和氧化吸收尾气处理系统关键设备腐蚀行为及控制措施研究"(20230306-03) （20230306-03）
