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冻融-干湿循环下碳化多源固废流态固化土耐久性及劣化机理

祁立柱 董晓强 崔德超 张倓嘉 殷军练 薛生国

太原理工大学学报2026,Vol.57Issue(4):683-698,16.
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太原理工大学学报2026,Vol.57Issue(4):683-698,16.DOI:10.16355/j.tyut.1007-9432.20260193

冻融-干湿循环下碳化多源固废流态固化土耐久性及劣化机理

Durability and Deterioration Mechanisms of Carbonation-Cured Flowable Solidified Soil Prepared from Multiple Industrial Solid Wastes During Freeze-Thaw and Wet-Dry Cycles

祁立柱 1董晓强 2崔德超 1张倓嘉 1殷军练 3薛生国4

作者信息

  • 1. 太原理工大学 土木工程学院,山西 太原
  • 2. 太原理工大学 土木工程学院,山西 太原||土木工程防灾与控制山西省重点实验室,山西 太原||太原科技大学 应用科学学院,山西 太原
  • 3. 煤炭工业太原设计研究院集团有限公司,山西 太原
  • 4. 中南大学 冶金民环境学院,湖南 长沙
  • 折叠

摘要

Abstract

[Purposes]To promote the use of industrial solid wastes such as red mud and carbide slag in engineering materials,a multi-source solid waste flowable solidified soil is prepared by using red mud,carbide slag,metakaolin,and magnesium slag as main constituents.[Methods]Carbonat-ed and non-carbonated specimens were produced and subjected to freeze-thaw cycles and wet-dry cy-cles,separtately.Changes in macroscopic appearance,mass loss rate,linear shrinkage,unconfined compressive strength,pH value,and electrical resistivity were examined,and the associated structur-al evolutions were analyzed with SEM and FTIR.[Results]The results indicate that both freeze-thaw cycling and wet-dry cycling lead to deterioration of the flowable solidified soil.During freeze-thaw cycles,the strength decreases continuously,whereas during wet-dry cycles it increases first and then declines.Carbonation improves the initial structure of the specimens.At the early stage of freeze-thaw cycling,mass loss and shrinkage reduce while early strength increases;however,this beneficial effect becomes less evident with increasing cycle number.During wet-dry cycles,the carbonated spec-imens show comparatively larger mass loss and shrinkage at later stages.Among different mixtures,the specimen containing 30%magnesium slag shows better stability with both environmental condi-tions.In both cases,the pH value decreases overall,and electrical resistivity shows a positive correla-tion with unconfined compressive strength.Microscopic observations further show that gel products gradually decrease during cyclic exposures,while pores and microcracks continue to develop,leading to progressive degradation of cementitious structure.

关键词

赤泥/流态固化土/碳化/耐久性/劣化机理

Key words

red mud/flowable solidified soil/carbonation/durability/deterioration mechanism

分类

建筑与水利

引用本文复制引用

祁立柱,董晓强,崔德超,张倓嘉,殷军练,薛生国..冻融-干湿循环下碳化多源固废流态固化土耐久性及劣化机理[J].太原理工大学学报,2026,57(4):683-698,16.

基金项目

国家自然科学基金资助项目(52378360,51978438),三晋英才计划科技创新领军人才项目 (52378360,51978438)

太原理工大学学报

1007-9432

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