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矿化剂对3D打印硅基陶瓷型芯微观结构及力学性能的影响

程毅明 李鹤 石小丽 管大伟 李飞

铸造2026,Vol.75Issue(8):855-861,7.
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铸造2026,Vol.75Issue(8):855-861,7.DOI:10.27014/j.cnki.zhuzao.2026.0110

矿化剂对3D打印硅基陶瓷型芯微观结构及力学性能的影响

The Influence of Mineralizers on the Microstructure and Mechanical Properties of 3D Printed Silica-Based Ceramic Cores

程毅明 1李鹤 2石小丽 1管大伟 3李飞3

作者信息

  • 1. 新疆大学材料科学与工程学院,新疆先进金属材料设计及应用重点实验室,新疆 乌鲁木齐 830046
  • 2. 新疆大学材料科学与工程学院,新疆先进金属材料设计及应用重点实验室,新疆 乌鲁木齐 830046||上海交通大学材料科学与工程学院,上海市先进高温材料及其精密成形重点实验室,上海 200240
  • 3. 上海交通大学材料科学与工程学院,上海市先进高温材料及其精密成形重点实验室,上海 200240
  • 折叠

摘要

Abstract

Silica-based ceramic cores exhibit excellent chemical solubility and core leaching performance,yet their inherently low mechanical strength makes them prone to cracking or deformation under the scouring of high-temperature molten metal,failing to meet the mechanical requirements of complex hollow turbine blades.This study proposes a strategy combining TiO2 mineralizer with DLP additive manufacturing to improve the densification behavior and mechanical properties of silica-based ceramics via compositional optimization.Ceramic cores with different TiO2 contents were fabricated by DLP stereolithography,and their microstructural evolution was analyzed by means of SEM,XRD and other methods,while the effect of sintering temperature on the flexural strength of ceramic cores was investigated.The results demonstrate that the addition of TiO2 can form a eutectic liquid phase with the matrix,promoting densification.The ceramic with 10wt.%TiO2 sintered at 1 300℃exhibits a significantly reduced open porosity of 14.28%±0.22%and a peak flexural strength of(65.46±1.96)MPa.The TiO2 content and the sintering temperature synergistically regulate the microstructure,and the 10wt.%TiO2 content significantly enhance the mechanical properties of the material by facilitating liquid-phase sintering.This work provides a reference basis for the compositional optimization of high-performance soluble ceramic cores.

关键词

陶瓷型芯/DLP光固化/TiO2掺杂/抗弯强度/微观结构/液相烧结/增材制造

Key words

ceramic core/DLP stereolithography/TiO2 doping/flexural strength/microstructure/liquid-phase sintering/additive manufacturing

分类

化学化工

引用本文复制引用

程毅明,李鹤,石小丽,管大伟,李飞..矿化剂对3D打印硅基陶瓷型芯微观结构及力学性能的影响[J].铸造,2026,75(8):855-861,7.

基金项目

先进材料—国家科技重大项目(2025ZD0609600). (2025ZD0609600)

铸造

1001-4977

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