物理学进展2026，Vol.46Issue(4)：174-201,28.DOI:10.13725/j.cnki.pip.2026.04.002
反铁电薄膜材料体系、研究现状及应用展望
Antiferroelectric thin film materials:research status and application prospects
摘要
Abstract
Research on antiferroelectric materials has spanned more than seventy years,and their unique field-induced phase transition behavior has demonstrated significant appli-cation value in dielectric energy storage devices,novel information devices,and thermal man-agement components.With advancements in thin-film growth techniques and the growing demand for miniaturization and integration of electronic devices,antiferroelectric thin films have attracted increasing attention.Numerous studies have shown that transitioning from bulk to thin-film forms,antiferroelectric materials exhibit novel physical properties distinct from their bulk counterparts,while also facing challenges such as the weakening or even disap-pearance of antiferroelectricity below a critical thickness due to size effects.In this context,this article systematically reviews the development history of antiferroelectric materials,from the physical origin of antiferroelectricity,the structural and phase transition characteristics of typ-ical material systems(including perovskite-structured PbZrO3,PbHfO3,NaNbO3,AgNbO3,and fluorite-structured HfxZr1-xO2),to their diverse functional device applications such as energy storage capacitors,antiferroelectric random access memory,antiferroelectric field-effect transistors,antiferroelectric tunnel junctions,and electrocaloric effects.We hope to attract more researchers to pay attention to the development of antiferroelectric thin films,to deeply explore their yet-to-be-fully-revealed microscopic mechanisms,and to jointly promote continu-ous breakthroughs in new materials,new devices,and new applications of antiferroelectric thin films.关键词
反铁电/介电储能/信息器件Key words
antiferroelectrics/dielectric energy storage/information devices分类
通用工业技术引用本文复制引用
马行健,黄新苗,李伟伟..反铁电薄膜材料体系、研究现状及应用展望[J].物理学进展,2026,46(4):174-201,28.基金项目
感谢国家自然科学基金(项目编号:92477107)、江苏省自然科学基金(项目编号:BK20250078)、中央高校基本科研业务费(项目编号:NE2025009)以及南京航空航天大学航空航天结构力学及控制全国重点实验室研究基金(项目编号:MCAS-I-0424G02和MCAS-I-0525K01)对本研究的资助. （项目编号:92477107）
