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水系石墨负极浆料CMC和SBR配伍性研究

王燕华 黄素洁 胡新发 杨伟

电源技术2026,Vol.50Issue(8):1446-1452,7.
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电源技术2026,Vol.50Issue(8):1446-1452,7.DOI:10.3969/j.issn.1002-087X.2026.08.007

水系石墨负极浆料CMC和SBR配伍性研究

Compatibility research of CMC and SBR in aqueous graphite anode slurries

王燕华 1黄素洁 2胡新发 3杨伟2

作者信息

  • 1. 广西安全工程职业技术学院 安全管理学院,广西 南宁 530100
  • 2. 广州大学 化学化工学院,广东 广州 510006
  • 3. 广州鹏辉能源科技股份有限公司,广东 广州 511483
  • 折叠

摘要

Abstract

To address the issues of insufficient slurry stability and fluctuating electrochemical perfor-mance caused by poor compatibility between CMC and SBR in aqueous graphite anode slurries,this study compared the effects of different CMC/SBR combinations on slurry dispersibility,electrode structure,and electrochemical performance through controlled experiments and process scale-up.The results show that the combination of Daicel 2200CMC and ZEON 451B(2200@451B-2)per-formed best,with a first-cycle specific capacity of 352.6 mAh/g in half-cell tests and capacity reten-tion remaining stable at over 80%after 500 cycles.In pouch full-cell tests,its performance was com-parable to that of the PVDF system,while exhibiting the fastest lithium-ion migration rate,lowest im-pedance,and densest SEI film.The system maintained excellent performance even after process scal-ing,demonstrating optimal compatibility and industrial scalability.

关键词

锂离子电池/石墨负极/粘结剂/羧甲基纤维素钠/丁苯橡胶

Key words

lithium-ion batteries/graphite anode/binder/CMC-Na/SBR

分类

信息技术与安全科学

引用本文复制引用

王燕华,黄素洁,胡新发,杨伟..水系石墨负极浆料CMC和SBR配伍性研究[J].电源技术,2026,50(8):1446-1452,7.

电源技术

1002-087X

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