江西科学2026，Vol.44Issue(4)：572-581,10.DOI:10.13990/j.issn1001-3679.2026.04.003
微塑料与磷界面相互作用机制及其环境效应研究进展
Interfacial Interaction Mechanisms and Ecological Implications of Microplastics and Phosphorus in Aquatic and Terrestrial Ecosystems:A Review
摘要
Abstract
As emerging macromolecular environmental pollutants,microplastics(MPs)and their interfacial interactions with the key biogenic element phosphorus(P)significantly im-pact nutrient cycling in aquatic and terrestrial environments.From the perspectives of inter-facial chemistry and physical chemistry,the adsorption thermodynamics and kinetics of phosphate onto MPs with diverse polymer matrices were systematically reviewed and the mi-croscopic coupling mechanisms modulated by multiple environmental factors were thorough-ly elaborated.The results indicated that pristine MPs exhibit low polarity and limited ad-sorption capacity.However,following environmental weathering(e.g.,photo-oxidation and hydrolysis),abundant oxygen-containing functional groups were generated on MP sur-faces accompanied by increased specific surface area.Accordingly,the phosphorus adsorp-tion pathway shifted from simple physical pore filling to complex interfacial chemical proces-ses dominated by chemical complexation(ligand exchange,hydrogen bonding)and bridging coprecipitation mediated by multivalent metal cations(Ca2+,Fe3+).Furthermore,such ad-sorption behaviors were strongly regulated by solution pH,ionic strength and dissolved or-ganic matter(DOM).Serving as highly mobile chemical carriers,MPs drastically interfered with the cross-interface transport and internal release of phosphorus via dynamic adsorption-de-sorption equilibria.Future research should strengthen in-situ characterization under cou-pled multi-stress conditions and explore physicochemical mechanisms in multi-pollutant composite systems.关键词
微塑料/磷/吸附机制/养分循环/生态风险Key words
microplastics/phosphorus/adsorption mechanism/nutrient cycling/ecological risk分类
化学化工引用本文复制引用
章卫,石先罗..微塑料与磷界面相互作用机制及其环境效应研究进展[J].江西科学,2026,44(4):572-581,10.基金项目
江西省水利厅科技计划项目(202425YBKT22,202526YBKT31) （202425YBKT22,202526YBKT31）
江西省教育厅科技课题(GJJ2409210,GJJ2509005). （GJJ2409210,GJJ2509005）
