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甲基卡伟晶岩形成的温压条件:来自矿物和全岩熔融模拟实验的约束

李子昂 吴言蔚 王国光 李万财 齐文翔 郑碧海 许志琴

地质学报2026,Vol.100Issue(8):2626-2637,12.
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地质学报2026,Vol.100Issue(8):2626-2637,12.DOI:10.19762/j.cnki.dizhixuebao.2026237

甲基卡伟晶岩形成的温压条件:来自矿物和全岩熔融模拟实验的约束

P-T conditions for the formation of the Jiajika pegmatites:Constraints from mineral assemblage and whole-rock melting experiments

李子昂 1吴言蔚 1王国光 1李万财 2齐文翔 1郑碧海 1许志琴1

作者信息

  • 1. 关键地球物质循环与成矿全国重点实验室,南京大学关键地球物质循环前沿科学中心,南京大学地质流体研究所,南京大学地球科学与工程学院,江苏 南京,210023
  • 2. 中国科学技术大学地球和空间科学学院,安徽 合肥,230026
  • 折叠

摘要

Abstract

Supercritical fluids are widely regarded as a key control on pegmatite genesis owing to their exceptionally high solubility,high mobility,and very low viscosity.However,it remains a matter of debate whether granitic melts and their exsolved fluids can become fully miscible and enter a supercritical state under the P-T(pressure-temperature)conditions of pegmatite formation.In this study,typical mineral assemblages and synthetic glasses prepared from whole-rock powders of the Jiajika pegmatites were investigated.In situ high-pressure and high-temperature(HP-HT)melting experiments were performed using a hydrothermal diamond-anvil cell(HDAC)to constrain the melt-fluid phase relations and evolution of natural pegmatite systems.The experimental results show that,at 0.4~0.84 GPa and 671~800℃,the melt occurs as discrete melt globules within the fluid phase,with sharp melt-fluid interfaces,in both the natural mineral assemblages and the glass systems containing abundant B-and Li-bearing fluxing components.No complete miscibility or supercritical-fluid behavior was observed.These results indicate that the critical curves for pegmatite-like systems established in previous studies using simplified H2O-albite glass systems with the excessive addition of B,F,and Na may underestimate the P-T conditions required for complete miscibility in compositionally complex natural pegmatite systems.The HP-HT experimental constraints from the Jiajika pegmatites suggest that during the petrogenesis and mineralization of ore-bearing pegmatites,the melt-fluid system likely persisted as two coexisting phases over a prolonged period.Rare-metal enrichment was controlled primarily by melt-fluid immiscibility and subsequent hydrothermal activity,rather than by supercritical processes.

关键词

伟晶岩/熔体-流体不混溶/热液金刚石压腔/甲基卡/川西

Key words

pegmatite/melt-fluid immiscibility/hydrothermal diamond-anvil cell/Jiajika/western Sichuan

引用本文复制引用

李子昂,吴言蔚,王国光,李万财,齐文翔,郑碧海,许志琴..甲基卡伟晶岩形成的温压条件:来自矿物和全岩熔融模拟实验的约束[J].地质学报,2026,100(8):2626-2637,12.

基金项目

本文为国家自然科学基金重大研究计划项目(编号92462301)和国家重点研发计划(编号2018YFA0702704)联合资助的成果. (编号92462301)

地质学报

0001-5717

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