合成材料老化与应用2026，Vol.55Issue(4)：50-52,3.
交联改性核桃壳的制备及表征
Preparation and Characterization of Cross-linked Modified Walnut Shell
摘要
Abstract
Using discarded walnut shells as raw materials,a series of modified walnut shell adsorbents were successfully prepared through alkali activation and epichlorohydrin cross-linking modification.The effects of cross-linking time on the structure and properties of the materials were systematically investigated.The materials were characterized by infrared spectroscopy(FT-IR),X-ray diffraction(XRD),and simultaneous thermal analysis(TG-DSC).The results indicated that cross-linked structures were successfully introduced during the modification process,and the crystallinity of the materials was significantly improved.A stable network structure formed through moderate cross-linking,and delays the initiation of thermal decomposition.Swelling performance test demonstrated that the sample cross-linked for 1 hour exhibited optimal water absorption,with a swelling ratio as high as 81.0％,providing a feasible approach for the resource utilization of walnut shells.关键词
核桃壳粉/环氧氯丙烷/交联改性/吸附剂/表征Key words
walnut shell powder/epichlorohydrin/cross-linking modification/adsorbent/characterization分类
化学化工引用本文复制引用
李凯斌,何欣怡,王丹,李朝阳,杨晨帆,张佳怡,杨尚霖..交联改性核桃壳的制备及表征[J].合成材料老化与应用,2026,55(4):50-52,3.基金项目
陕西省大学生创新创业训练项目(S202511396099) （S202511396099）
博士科研启动基金(23SKY018) （23SKY018）
三秦英才引进计划区域青年项目(25RCZX03) （25RCZX03）
陕西省自然科学基础研究计划资助项目(2025JC-YBQN-200) （2025JC-YBQN-200）
陕西省教育厅项目(24JK0422). （24JK0422）
