可再生能源2026，Vol.44Issue(8)：1012-1021,10.
碳掺杂Co3O4催化剂电催化氧化5-羟甲基糠醛的性能研究
Study on the performance of carbon-doped Co3O4 catalysts for the electrochemical oxidation of 5-hydroxymethylfurfural
摘要
Abstract
This study reports a series of carbon-modified Co3O4/NF(Co3O4/NF@Cx)catalysts.The morphology,phase composition,electronic structure,and electrochemical properties of the prepared materials were analyzed using various characterization techniques,including scanning electron microscopy,transmission electron microscopy,X-ray photoelectron spectroscopy,X-ray diffraction,and electrochemical testing(electrochemical active surface area and electrochemical impedance spectroscopy).The results indicate that 0.1 mol/L glucose is the optimal precursor concentration.The resulting Co3O4/NF@C0.1 exhibits a nanosheet structure,which enlarges the electrochemically active surface area,modulates the electronic structure,and accelerates charge transfer kinetics.Consequently,Co3O4/NF@C0.1 delivers excellent electrocatalytic performance for HMF oxidation:the potential required to reach 10 mA/cm2 is 273 mV lower than that for OER,with FDCA selectivity of>95％and faradaic efficiency of>94％.Meanwhile it also exhibits high HER activity.Furthermore,the catalyst retains 98％HMF conversion rate and excellent stability after five consecutive cycles.关键词
生物质/5-羟甲基糠醛/2,5-呋喃二甲酸/电化学催化Key words
biomass/5-hydroxymethylfurfural/2,5-furanediformic acid/electrochemical catalysis分类
能源科技引用本文复制引用
高阳,程耘康,胡雨竹,孟少华,赵建生,林天驰,刘庆玉..碳掺杂Co3O4催化剂电催化氧化5-羟甲基糠醛的性能研究[J].可再生能源,2026,44(8):1012-1021,10.基金项目
辽宁省科学技术厅项目(2025-BS-0517). （2025-BS-0517）
