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化学气相沉积法在铁、铁合金及纳米颗粒上制备石墨烯:生长、表征、应用与挑战

Justina Teye Hema Ramsurn

新型炭材料(中英文)2026,Vol.41Issue(4):806-839,34.
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新型炭材料(中英文)2026,Vol.41Issue(4):806-839,34.DOI:10.1016/S1872-5805(26)61107-9

化学气相沉积法在铁、铁合金及纳米颗粒上制备石墨烯:生长、表征、应用与挑战

CVD graphene on iron,iron alloys and nanoparticles:a review of its growth,characterization,applications and challenges

Justina Teye 1Hema Ramsurn1

作者信息

  • 1. The Russell School of Chemical Engineering,The University of Tulsa,Oklahoma 74104,USA
  • 折叠

摘要

Abstract

Graphene's outstanding electrical,thermal,mechanical,and chemical properties make it a promising material for electronics,energy storage,protective coat-ings,catalysis,and environmental remediation.Neverthe-less,its large-scale use is hindered by high synthesis costs,process complexities,and integration issues.Among the available methods for its production,chemical vapor de-position(CVD)on metals is the most scalable,in which copper is widely used because of its low carbon solubility and excellent monolayer control.However,Cu substrates are costly($8-10/kg),subsequent transfer steps introduce defects,and the obtained graphene is poorly matched to structural components.Iron-based substrates provide an at-tractive alternative,offering much lower material cost,dir-ect compatibility with steel infrastructure,reduced growth temperatures,and intrinsic functionalities such as magnet-ism and catalytic activity that enable new applications.The growth of graphene on pure iron,iron alloys,and iron-Based on nanoparticles is analyzed,focusing on growth mechanisms,substrate engineering,and characterization approaches tailored to specific challenges like carbide formation.Ap-plications including corrosion-resistant coatings,electronics,energy storage,catalysis,water treatment,and electromagnetic shielding are considered.Despite the limitation of high carbon solubility,iron can be exploited for controlled multilayer forma-tion which is useful for barrier and energy applications,while alloying and process control enable the production of tunable mono layer or few-layer films,making iron-based CVD graphene a versatile,cost-effective platform.

关键词

CVD石墨烯/铁基衬底/生长机理/衬底工程/钢一体化

Key words

CVD graphene/Iron-based substrates/Growth mechanism/Substrate engineering/Steel integration

分类

化学化工

引用本文复制引用

Justina Teye,Hema Ramsurn..化学气相沉积法在铁、铁合金及纳米颗粒上制备石墨烯:生长、表征、应用与挑战[J].新型炭材料(中英文),2026,41(4):806-839,34.

新型炭材料(中英文)

1007-8827

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