中国造纸2026，Vol.45Issue(8)：95-103,9.DOI:10.11980/j.issn.0254-508X.2026.08.010
竹纤维素基黏附材料的制备及其湿组织黏附性能研究
Study on the Fabrication of Bamboo Cellulose-based Adhesive Materials and Its Wet Tissue Adhesion Property
摘要
Abstract
To achieve high-value applications of bamboo,and to address the poor wet adhesion performance of current cellulose-based tissue adhesives,carboxymethyl cellulose(CMC)was prepared from bamboo cellulose fibers in this study.Through methacrylate esterification mod-ification,a photo-crosslinkable carboxymethyl cellulose methacrylate(CMC-MA)was synthesized,then it was copolymerized with acrylic acid(AA)and the catechol-containing monomer dopa(DMA)under blue light to construct a bamboo cellulose-based adhesive material which fea-tured a multi-crosslinked network comprising covalent bonds,hydrogen bonds,and π-π stacking.The study systematically investigated the reg-ulation of material properties by varying the CMC-MA mass fraction(0.5%～2.0%).The resulting bamboo cellulose-based adhesive material ex-hibited equilibrium swelling ratios ranging from 6.3 to 21.3 g/g,tensile strengths from 3.1 to 5.7 MPa,and elongations at break from 180.4%to 306.5%.The optimized bamboo cellulose-based adhesive material demonstrated strong adhesion to moist porcine skin,with a shear strength of 23 kPa and an interfacial toughness of 150 J/m2,outperforming commercial tissue adhesives.The results of ex vivo organ sealing tests showed that the bamboo cellulose-based adhesive material withstood 200 cycles of cyclic expansion and contraction in a porcine heart model without detaching,and achieved rapid sealing under light pressure within 5 s in a simulated gastric acid leakage model,maintaining efficacy for 48 h,with no cytotoxicity.关键词
竹纤维/纤维素改性/黏附材料/湿组织黏附Key words
bamboo fiber/cellulose modification/adhesive material/wet tissue adhesion分类
轻工纺织引用本文复制引用
陈礼辉,卢生昌,吴慧,渠昊帆..竹纤维素基黏附材料的制备及其湿组织黏附性能研究[J].中国造纸,2026,45(8):95-103,9.基金项目
国家自然科学基金(22278071,32401680). （22278071,32401680）
