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A spirosilane ligand induced highly enantioselective Rh-catalyzed cycloisomerization of 1,6-enynes

Zequn Tan Fei Hou Jie Zeng Fan Yang Tongyao Zhou Guo-Hua Hu Yajiao Zhang Fener Chen

Green Synthesis and Catalysis2026，Vol.7Issue(3)：P.351-354,4.

Green Synthesis and Catalysis2026，Vol.7Issue(3)：P.351-354,4.DOI:10.1016/j.gresc.2024.07.004

A spirosilane ligand induced highly enantioselective Rh-catalyzed cycloisomerization of 1,6-enynes

Zequn Tan ¹Fei Hou ¹Jie Zeng ²Fan Yang ¹Tongyao Zhou ¹Guo-Hua Hu ³Yajiao Zhang ¹Fener Chen⁴

作者信息

1. Engineering Center of Catalysis and Synthesis for Chiral Molecules,Department of Chemistry,Fudan University,Shanghai 200433,China
2. Pharmaceutical Research Institute,Wuhan Institute of Technology,Wuhan 430205,China
3. Universite de Lorraine,CNRS,LRGP,Nancy F-54001,France
4. Engineering Center of Catalysis and Synthesis for Chiral Molecules,Department of Chemistry,Fudan University,Shanghai 200433,China Shanghai Engineering Center of Industrial Asymmetric Catalysis for Chiral Drugs,Shanghai 200433,China Institute of Flow Chemistry and Engineering,College of Chemistry and Materials,Jiangxi Normal University,Nanchang 330022,China Pharmaceutical Research Institute,Wuhan Institute of Technology,Wuhan 430205,China
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摘要

关键词

Rhodium/1,6-Enynes/Cycloisomerization/Spirosilane diphosphine ligands/DFT calculate

分类

化学化工

引用本文复制引用

Zequn Tan,Fei Hou,Jie Zeng,Fan Yang,Tongyao Zhou,Guo-Hua Hu,Yajiao Zhang,Fener Chen..A spirosilane ligand induced highly enantioselective Rh-catalyzed cycloisomerization of 1,6-enynes[J].Green Synthesis and Catalysis,2026,7(3):P.351-354,4.

基金项目

support from the National Natural Science Foundation of China(No.22077018)is gratefully acknowledged. （No.22077018）

Green Synthesis and Catalysis

ISSN：2666-5549

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