高压物理学报2026，Vol.40Issue(9)：3-27,25.DOI:10.11858/gywlxb.20261109
金刚石纳米线的结构性能和高压合成研究进展
Advances in Structural Properties and High-Pressure Synthesis of Diamond Nanothreads
摘要
Abstract
Diamond nanothreads are one-dimensional crystalline nanomaterials formed by the polymerization of organic molecules under high pressure.Their sp3-hybridized carbon framework endows them with exceptional mechanical,thermal,and electrical properties.This paper systematically reviews the progress in structural prediction,synthesis strategies,and property studies of this material.Theoretical investigations have demonstrated that diamond nanothreads possess wide band gaps,high carrier mobility,and excellent mechanical performance,and that their electronic structure can be effectively tuned through heteroatom doping,defect introduction,and lattice strain.Regarding the synthesis,a variety of ordered crystalline nanothreads have been successfully prepared via high-pressure solid-state reactions using precursors such as benzene,fluorobenzene,pyridazine,s-triazine,and cubane.Through rational precursor molecular design,cocrystal engineering,and regulation of reaction conditions,functionalization and heteroatom doping synthesis have been realized.In recent years,the successful preparation of polymer single crystals with sizes up to hundreds of micrometers using 1-naphthoic acid as the precursor has enabled,for the first time,the direct measurement of anisotropic thermal conductivity.This paper also provides an outlook on future research directions concerning precise structural control,multifunctionalization,and reduced-pressure synthesis.关键词
金刚石纳米线/纳米碳材料/高压化学/压力诱导聚合Key words
diamond nanothreads/nanocarbon materials/high-pressure chemistry/pressure-induced polymerization分类
数理科学引用本文复制引用
方源,汪雅洁,郑海燕,李阔..金刚石纳米线的结构性能和高压合成研究进展[J].高压物理学报,2026,40(9):3-27,25.基金项目
国家重点研发计划(2023YFA1406200) （2023YFA1406200）
国家自然科学基金(22022101) （22022101）
