发光学报2026，Vol.47Issue(8)：1450-1457,8.DOI:10.37188/CJL.20260098
基于松香D-A骨架TICT-AIE协同效应的双通道发射调控及性能研究
Dual-channel Emission Regulation and Performance Based on Synergistic Effect of TICT-AIE in Rosin D-A Skeleton
摘要
Abstract
In this study,a novel luminescent derivative A-TPA-N with both TICT and AIE properties was success‑fully constructed by introducing triphenylamine donor units and naphthalimide acceptor units into the rigid skeleton of dehydroabietic acid.The luminescence mechanism was analyzed by a mixed-solvent fluorescence testing system,with a focus on the dual-channel emission behavior under different excitation wavelengths,as well as the regulation rules of solvent polarity and aggregation effect on the LE state and ICT state luminescence.Moreover,the natural chi‑ral skeleton successfully induced circularly polarized luminescence.This work provides a new strategy for the devel‑opment of high-performance natural biochiral luminescent materials,and these materials have potential application value in fields such as display and bioimaging.关键词
双通道发射/扭曲的分子内电荷转移/聚集诱导发光/松香Key words
dual-channel emission/twisted intramolecular charge transfer/aggregation-induced emission/rosin分类
数理科学引用本文复制引用
赵兰兰,邱贝贝,李念书,何心语,梅群波..基于松香D-A骨架TICT-AIE协同效应的双通道发射调控及性能研究[J].发光学报,2026,47(8):1450-1457,8.基金项目
国家自然科学基金(61675088,61675089,62075103) （61675088,61675089,62075103）
南京邮电大学自然科学基金(NY221090)Supported by National Natural Science Foundation of China(61675088,61675089,62075103) （NY221090）
Nanjing University of Posts&Telecommunications Culturing Project(NY221090) （NY221090）
