燃料化学学报（中英文）2026，Vol.54Issue(9)：20-35,16.DOI:10.3724/2097-213X.2026.JFCT.0002
高效甲酸脱氢催化剂的活性调控策略与机理探讨
Exploration of activity control strategies and mechanisms for efficient HCOOH dehydrogenation catalysts
摘要
Abstract
Formic acid(HCOOH)is taken as a promising H2 carrier,which has attracted wide concern as a result of high hydrogen content,low toxicity,high stability and simple byproducts.In this paper,we review the catalytic activity of Pd nanoparticles and Pd alloy metal nanoparticles loaded with inert carriers,reduced oxides,metal organic framework materials,carbon materials,as well as molecular sieves.Further,we summarize the reaction mechanism of the HCOOH dehydrogenation reaction driven by thermal energy,photo energy and photo-thermal energy.Finally,we provide the prospects to the challenges faced by HCOOH dehydrogenation reaction from the view of improving the utilization of active metals,using theoretical calculations to deeply understand coupling effects,utilizing advanced techniques to explore reaction mechanisms and realizing carbon cycling.关键词
甲酸脱氢/纳米粒子/粒子尺寸/配位结构/反应机理Key words
HCOOH dehydrogenation/nanoparticle/particle size/coordination structure/reaction mechanism分类
化学化工引用本文复制引用
袁晋,东子涵,段忠伟,张馨予,贾冰吉,武美霞,崔艳霞,李作鹏..高效甲酸脱氢催化剂的活性调控策略与机理探讨[J].燃料化学学报（中英文）,2026,54(9):20-35,16.基金项目
Supported by Natural Science Foundation of Shanxi Province(202503021212233)and Datong Natural Science Foundation(2024065).山西省自然科学基金(202503021212233)和大同市自然基金(2024065)资助 （202503021212233）
