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湿式球磨耦合多步浸出处理铝电解槽废阴极炭研究

孙想旭 张明杰 李朝旭 李怡招 杨超

世界有色金属Issue(15):7-9,3.
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世界有色金属Issue(15):7-9,3.

湿式球磨耦合多步浸出处理铝电解槽废阴极炭研究

Study on Treatment of Spent Cathode Carbon from Aluminum Reduction Cell by Wet Ball Milling Coupled with Multi-step Leaching

孙想旭 1张明杰 2李朝旭 3李怡招 3杨超1

作者信息

  • 1. 石油天然气精细化工教育部/自治区重点实验室,新疆大学化工学院,新疆 乌鲁木齐 830017
  • 2. 新疆新能源(集团)环境发展有限公司,新疆 乌鲁木齐 830063||新疆新能源(集团)准东环境发展有限公司,新疆 昌吉 831799
  • 3. 电子科技大学长三角研究院(湖州),浙江 湖州 313001
  • 折叠

摘要

Abstract

A wet ball milling pretreatment was coupled with multi-step leaching for spent cathode carbon.The effect of ball milling conditions on the deashing of spent cathode carbon was investigated,followed by phase analysis of residual impurities and by the desalination of milled solution waste.The results showed that the ash content of spent cathode carbon decreased from 44.78%to 6.15%,when treated with the optimized conditions including zirconia ball size(1.0~1.2 mm),feeding ratio(2 g spent cathode carbon/24 g water),milling speed(400 rpm),and milling time(6 h).Furthermore,the particle morphology was disaggregated from bulk aggregates to carbon nanoplatelets with reduced size.XRD analysis showed that a small amount of the NaAlSiO4 impurity remained in the treated carbon powder.The solution waste from ball milling treatment of spent cathode carbon was concentrated to separate out sodium fluoride with relatively high purity.

关键词

废阴极炭/脱灰/湿式球磨/多步浸出/炭纳米片

Key words

Spent cathode carbon/Deashing/Wet ball milling/Multi-step leaching/Carbon nanoplatelet

分类

矿业与冶金

引用本文复制引用

孙想旭,张明杰,李朝旭,李怡招,杨超..湿式球磨耦合多步浸出处理铝电解槽废阴极炭研究[J].世界有色金属,2026,(15):7-9,3.

基金项目

本工作得到了新疆维吾尔自治区重点研发计划(项目编号:2021B03005)的资金支持. (项目编号:2021B03005)

世界有色金属

1002-5065

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