天津工业大学学报2026，Vol.45Issue(4)：1-8,8.DOI:10.3969/j.issn.1671-024x.2026.04.001
中空纤维陶瓷膜介导微气泡制备与CO2合成环状碳酸酯
Microbubble generation mediated by hollow fiber ceramic membrane for the synthesis of cyclic carbonates from CO2
摘要
Abstract
To address the challenges in the controllable preparation of microbubbles and their application in chemical reac-tion intensification,a heterogeneous membrane reactor was constructed using hollow fiber ceramic membranes for efficient controllable generation and rapid characterization of microbubbles.Furthermore,its application in the synthesis of cyclic carbonates from CO2 was investigated.The effects of membrane length,pore size,number of membranes,liquid-to-gas ratio,and gas-liquid flow mode on microbubble size were systematically investigated.The experimental results showed that when the membrane length was 15 cm,the pore size was 0.3 μm,the single-layer membrane,the liquid-to-gas ratio was 18,and the liquid flowed inside the membrane while gas flowed outside,microbubbles with a diameter of 46-152 μm could be continuously generated.When this membrane re-actor setup was employed for cyclic carbonate synthesis through CO2 cycloaddition,epichlorohydrin conversion up to 81.9%and a cyclic carbonate yield of 74.05%could be obtained at ambient temperature and atmospheric pressure.关键词
微气泡/非均相反应器/中空纤维陶瓷膜/CO2环加成反应Key words
microbubbles/heterogeneous reactor/hollow fiber ceramic membrane/CO2 cycloaddition reaction分类
化学化工引用本文复制引用
王志刚,廖芳,王明明,代淑梅,谭小耀,张匀..中空纤维陶瓷膜介导微气泡制备与CO2合成环状碳酸酯[J].天津工业大学学报,2026,45(4):1-8,8.基金项目
国家自然科学基金项目(22178271,22178269,22208009) （22178271,22178269,22208009）
河北省省级科技计划资助项目(246Z4602G) （246Z4602G）
