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配煤对煤灰熔融温度和黏温特性的影响

冯斌 赵薇 李伟 宋旭东 白永辉 于广锁

宁夏大学学报(自然科学版中英文)2026,Vol.47Issue(5):451-457,7.
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宁夏大学学报(自然科学版中英文)2026,Vol.47Issue(5):451-457,7.DOI:10.20176/j.cnki.nxdz.20260906

配煤对煤灰熔融温度和黏温特性的影响

The Impact of Coal Blending on the Melting Temperature and Viscosity Characteristics of Coal Ash

冯斌 1赵薇 2李伟 3宋旭东 2白永辉 2于广锁4

作者信息

  • 1. 宁夏大学 省部共建煤炭高效利用与绿色化工国家重点实验室,宁夏 银川 750021||兖州煤业榆林能化有限公司,陕西 榆林 718000
  • 2. 宁夏大学 省部共建煤炭高效利用与绿色化工国家重点实验室,宁夏 银川 750021
  • 3. 兖州煤业榆林能化有限公司,陕西 榆林 718000
  • 4. 宁夏大学 省部共建煤炭高效利用与绿色化工国家重点实验室,宁夏 银川 750021||兖州煤业榆林能化有限公司,陕西 榆林 718000||华东理工大学 洁净煤技术研究所,上海 200030
  • 折叠

摘要

Abstract

To address the mismatch between the melting temperature(tm)and viscosity(η)of coal ash in the Yulin area and the requirements of gasification process,coal blending was conducted using six types of local coal(Jinjitan slack coal and five cleaned coals)to study the effect of coal blending on tm and η.The results indi-cate that with an increase in the mass of cleaned coal(m)blended,the tm and η of coal ash slag exhibit a nonlin-ear decreasing trend.FactSage simulation results show that as the mass fraction of alkaline components(wa)in the coal ash slag increases,the amount of low-melting-point minerals(such as CaAl2Si2O8)increases,leading to a decrease in the tm of coal ash slag.Although J8H2 coal ash exhibits a glassy slag state,its η is relatively high,which can easily lead to slagging in the gasifier.With an increase in the mass of blended cleaned coal(m),the coal ash slag shows a crystalline slag state,but the temperature range corresponding to η=2.5-25.0 Pa·s is expanded,which is beneficial for the stable operation of the gasifier.The calculation results of non-bridging oxygen bonds and bridging oxygen bonds(nNBO/nBO)show that an increase in the mass of blended cleaned coal(m)reduces the stability of the silicate network structure of coal ash slag,resulting in a decrease in η.Coal blending effectively regulates the tm and η of Yulin coal,providing a theoretical basis for its efficient utili-zation in gasifiers.

关键词

配煤/煤灰熔融温度/黏温特性/非桥氧键与桥氧键

Key words

coal blending/melting temperature of coal ash/viscosity temperature characteristics/non-bridging oxygen bonds and bridging oxygen bonds

分类

化学化工

引用本文复制引用

冯斌,赵薇,李伟,宋旭东,白永辉,于广锁..配煤对煤灰熔融温度和黏温特性的影响[J].宁夏大学学报(自然科学版中英文),2026,47(5):451-457,7.

基金项目

国家自然科学基金资助项目(22108132) (22108132)

宁夏大学学报(自然科学版中英文)

0253-2328

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