宁夏大学学报（自然科学版中英文）2026，Vol.47Issue(5)：458-477,20.DOI:10.20176/j.cnki.nxdz.20260907
硅基负极体系从液态电解质到全固态电解质的转变:界面构效关系与调控策略
Interfacial Structure-Property Relationships and Regulation Strategies of Transition from Liquid to All-Solid-State Electrolytes for Silicon-Based Anode Systems
摘要
Abstract
Following the central theme of"electrolyte regulation-interfacial evolution-performance enhance-ment",this review systematically summarizes the key challenges and recent progress of silicon-based anodes in liquid,quasi-solid-state,and all-solid-state electrolyte systems.Particular attention is paid to the synergistic effects of prelithiation,binder optimization,and electrolyte-formulation regulation in liquid electrolyte systems;the advantages of solid‒liquid cooperation in mitigating the volume expansion of silicon-based anodes in quasi-solid-state electrolyte systems from chemically dominated side reactions to dominated contact failure.The key strategies involving multiscale structural design,interfacial engineering,and cell-level synergistic optimization are summarized.The prospects for the commercial application of silicon-based anodes in high-energy-density battery systems are also discussed.This review provides a useful reference for understanding the interfacial structure‒property relationships and regulation mechanisms of silicon-based anodes under different electrolyte systems,and may also offer guidance for the development of other high-capacity anode materials.关键词
硅基负极/电解质优化/界面工程/固态电池/锂离子电池Key words
silicon-based anode/electrolyte design/interface engineering/solid-state batteries/lithium-ion batteries分类
通用工业技术引用本文复制引用
马萍,丁云云,吕昆育,李康宁,吴建波,吴玉花,马晓宝,白红存,张慧..硅基负极体系从液态电解质到全固态电解质的转变:界面构效关系与调控策略[J].宁夏大学学报（自然科学版中英文）,2026,47(5):458-477,20.基金项目
国家自然科学基金资助项目(52367023) （52367023）
宁夏自然科学基金资助项目(2026AAC020033) （2026AAC020033）
