应用化学2026，Vol.43Issue(9)：1359-1376,18.DOI:10.19894/j.issn.1000-0518.260037
芳环及芳杂环化合物加氢用贵金属催化剂的研究进展
Research Progress of Noble Metal Catalysts for Hydrogenation of Aromatic and Heteroaromatic Compounds
摘要
Abstract
As a zero-pollution clean energy,hydrogen storage and transportation restrict its large-scale application.The core of liquid organic hydrogen carrier(LOHC)technology lies in hydrogenation of aromatic and heteroaromatic compounds,where noble metal catalysts play a decisive role in determining the application efficiency of this technology.This review summarizes the research progress of noble metal catalysts in hydrogenation of aromatic compounds(benzene,toluene)and heteroaromatic compounds(N-ethylcarbazole,indole,quinoline).It focuses on the regulatory mechanisms of support engineering(mesoporous materials,carbon-based supports,metal oxides),single-atom dispersion,bimetallic synergy,and hydrogen spillover effects on catalyst performance.These studies optimize hydrogen storage efficiency in LOHC systems through synergistic regulation of atomic-level active sites and support functionalization,providing new ideas to address high costs and high-temperature sintering of noble metals,and laying a foundation for the economic and industrial application of the hydrogen energy industry chain.关键词
芳环及芳杂环化合物/液态有机氢载体/加氢/贵金属催化剂/载体Key words
Aromatic and heteroaromatic compounds/Liquid organic hydrogen carrier/Hydrogenation/Noble metal catalysts/Support分类
化学化工引用本文复制引用
赵耀洪,王君,林浩,刘伟,刘英杰,金铭,何晓辉..芳环及芳杂环化合物加氢用贵金属催化剂的研究进展[J].应用化学,2026,43(9):1359-1376,18.基金项目
南方电网公司科技项目(Nos.032000KC24080051,GDKJXM20240712)、国家自然科学基金优秀青年科学基金(No.2020YFA0210900)、国家自然科学基金(Nos.22422815,U22A20428)、广东省自然科学基金杰出青年项目(No.2022B1515020035)和山西省科技创新人才团队专项计划(No.202304051001007)资助 Supported by the Southern Power Grid Company's Scientific Research Project(Nos.032000KC24080051,GDKJXM20240712),the National Natural Science Foundation of China Outstanding Young Scientist Fund(No.2020YFA0210900),the National Natural Science Foundation of China(Nos.22422815,U22A20428),Guangdong Province Natural Science Foundation Outstanding Young Project(No.2022B1515020035)and Shanxi Province Special Plan for Innovation and Talent Team Construction(No.202304051001007) （Nos.032000KC24080051,GDKJXM20240712）
