物理化学学报2026，Vol.42Issue(10)：89-112,24.DOI:10.1016/j.actphy.2026.100248
具有"钢筋混凝土"结构和优异电磁波吸收性能的 Fe3O4/Ti3C2Tx MXene/CF@PANI复合材料
Strengthening of Fe3O4/Ti3C2Tx MXene/CF@PANI composites with'reinforced concrete'structure and high electromagnetic wave absorption performance
摘要
Abstract
Ti3C2Tx MXene's application as an efficient electromagnetic wave absorber(EWA)is hindered by its high reflection,low absorption,and poor mechanical strength.Inspired by structural engineering,we propose a heterogeneous assembly strategy to construct a novel'reinforced concrete'structured Fe3O4/Ti3C2Tx MXene/CF@PANI(CPFT)composite.Through multi-scale structural design and interface regulation,the integration of mechanical enhancement and electromagnetic functionality has been achieved.The in-situ polymerized CF@PANI core-shell unit acts as both a reinforcing skeleton and a conductive bridge,enhancing mechanical stability and conductive loss.Simultaneously,mediated by polydopamine,Fe3O4 grows in-situ between the interlayers and on the surface of Ti3C2Tx MXene,forming a concrete-like matrix.The components self-assemble through electrostatic and hydrogen bonding interactions,resulting in a heterostructure with excellent interfacial compatibility.This significantly promotes interfacial charge accumulation and multiple polarization effects,optimizes impedance matching,extends the propagation and dissipation path of electromagnetic waves within the material,and achieves effective synergy between dielectric and magnetic losses.As a result,at 13.76 GHz,the CPFT-0.75 exhibits a minimum reflection loss of −37.34 dB and an effective absorption bandwidth of 3.28 GHz at a thickness of only 1.5 mm.Additionally,the CPFT-1.0 possesses good mechanical properties,with a measured Young's modulus of 20.8 MPa,tensile strength of 3.63 MPa,and elongation at break of 10.98%.This study presents a novel MXene-based functional material design through the integration of magnetic,conductive,and 2D nanomaterials within a hierarchical architecture that delivers a dual enhancement in both EWA and mechanical performance.关键词
Ti3C2Tx MXene/电磁波吸收/表面-界面效应/微结构设计/力学性能Key words
Ti3C2Tx MXene/Electromagnetic wave absorption/Surface-interface effect/Micro-structure design/Mechanical property分类
化学化工引用本文复制引用
翟钰琦,刘梦竹,胡峻豪,王永鹏..具有"钢筋混凝土"结构和优异电磁波吸收性能的 Fe3O4/Ti3C2Tx MXene/CF@PANI复合材料[J].物理化学学报,2026,42(10):89-112,24.基金项目
本研究得到吉林省科学技术厅资助(YDZJ202301ZYTS307) （YDZJ202301ZYTS307）
吉林省教育厅资助(JJKH20261290KJ). （JJKH20261290KJ）
