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脉冲电泳沉积制备电致变色WO3薄膜

蓝满玉 王晨 汪炜

电子元件与材料2011,Vol.30Issue(2):43-46,49,5.
电子元件与材料2011,Vol.30Issue(2):43-46,49,5.

脉冲电泳沉积制备电致变色WO3薄膜

Preparation of electrochromic WO3 films by pulsed electrophoretic deposition

蓝满玉 1王晨 1汪炜2

作者信息

  • 1. 福州大学,材料科学与工程学院,福建,福州,350108
  • 2. 福州大学,表面纳米技术研究所,福建,福州,350108
  • 折叠

摘要

Abstract

The process parameters employed for the pulsed electrophoretic deposition of WO3 films were optimized by the orthogonal design method. The eloctrochromic properties of the WO3 films prepared under the optimized condition were studied through characterizing the microstructure, transmission spectra and cyclic voltammogram of the films. The optimal process parameters for the pulsed electrophoretic deposition of WO3 films are: average current density = 0.2× 10-3 A/cm2,deposition time = 6 min, duty cycle = 75% and pulse period = 10 ms. For the WO3 films prepared under the optimized condition, they are amorphous film with a thickness of about 251 nm, their transmission modulation (△T) reaches 76%~80% in the visible region (550~800 nm), and they exhibit high electrochemical activity with an ion storage capacity of 27.8× 10-3 C/cm2; However, their bleaching/coloring responses are asymmetric and reversibility is relatively low (75.1%).

关键词

脉冲电泳沉积/WO3薄膜/电致变色/正交设计

Key words

pulse electrophoretic deposition/ WO3 film/ electrochromism/ orthogonal design.

分类

数理科学

引用本文复制引用

蓝满玉,王晨,汪炜..脉冲电泳沉积制备电致变色WO3薄膜[J].电子元件与材料,2011,30(2):43-46,49,5.

基金项目

福建省自然科学基金资助项目(No.E0710005) (No.E0710005)

电子元件与材料

OA北大核心CSCDCSTPCD

1001-2028

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