现代食品科技2011，Vol.27Issue(7)：856-860,869,6.
高效液相色谱法测定蔬菜中8种氨基甲酸酯类农药残留
Determination of Eight Carbamate Pesticides in Vegetables by High Performance Liquid Chromatography
摘要
Abstract
A new method for the simultaneous determination of eight carbamate pesticides in Chinese cabbage, pepper, egg-plant,tomato, Chinese spinach, bitter gourd, cabbage and cowpea by high performance liquid chromatography was developed. Eight carbamate pesticides was extracted froom the samples by acetonitrile, salted, purified with LC-NH2 column and determined by high performance liquid chromatography using post-column derivatization with fluorescence detector. The proposed methods showed a good linearity between analytical signal in the range of 0.1～1.0 mg/L with the linear correlation coefficients of 0.99943～0.99992 and limits of detection of 0.008～0.01 mg/kg. The average recoveries obtained from samples spiked with standards at concentration level 0.1 mmg/kg and 0.2 mmg/kg were in the range of 79.4％～119.0％ and 81.2％ ～115.5％, respectively, with relative standard deviations of 2.5％ ～11.5％ and 2.8％～8.1％,respectively. The method was accurate, reliable, and can be used for determination carbamate pesticides in vegetables.关键词
高效液相色谱法/柱后衍生/氨基甲酸酯类农药/蔬菜Key words
high performance liquid chromatography/ post-column derivatization/ carbamate pesticides/ vegetables引用本文复制引用
邵金良,黎其万,刘宏程,佴注,兰珊珊,梅文泉,杜丽娟,樊建麟..高效液相色谱法测定蔬菜中8种氨基甲酸酯类农药残留[J].现代食品科技,2011,27(7):856-860,869,6.基金项目
云南省社会发展科技计划项目(2008CD181) （2008CD181）
云南省科技创新强省计划项目(2009AB002). （2009AB002）
