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酚醛树脂基炭膜的制备与性能研究

杨立军 张金海

沈阳农业大学学报2011,Vol.42Issue(2):247-250,4.
沈阳农业大学学报2011,Vol.42Issue(2):247-250,4.

酚醛树脂基炭膜的制备与性能研究

Preparation of Phenolic-resin-based Carbon Membrane and Its Separation Performance

杨立军 1张金海1

作者信息

  • 1. 沈阳农业大学高职学院,沈阳110122
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摘要

Abstract

Vacuum-assisted coating (VC) was employed to prepare carbon membrane on porous α-Al2O3 tube using commercial phenol resin as precursor, and the effect of vacuum degree was investigated. Results showed that the VC method was more effective (vacuum degree = 0.6 Mpa) for the preparation of uniform carbon membrane compared with the conventional method. Single-gas permeation test indicated that with the increase of vacuum degree, the gas permeance decreased and the selectivity exhibited the maximum. The CO2/CH4 (50/50) mixture permeation test showed that the carbon membrane had CO2 permeance of 1.4×l0-7 mol·Pa-1·m-2·s-1 and CO3/CH4 selectivity of 48.3, higher than the Knudsen value. The scanning electron microscope revealed that the membrane was dense, continuous, with a thickness of 4 μm.

关键词

酚醛树脂/炭膜/真空辅助/气体分离

Key words

phenol ic-resin/carbon membrane/vacuum-assisted/gas separation

分类

化学化工

引用本文复制引用

杨立军,张金海..酚醛树脂基炭膜的制备与性能研究[J].沈阳农业大学学报,2011,42(2):247-250,4.

沈阳农业大学学报

OA北大核心CSCDCSTPCD

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