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MLPB-PEG400/LiClO4固体聚合物电解质的电化学性能研究

赵鸽 王金伟 刘建

电子元件与材料2011,Vol.30Issue(9):36-39,4.
电子元件与材料2011,Vol.30Issue(9):36-39,4.

MLPB-PEG400/LiClO4固体聚合物电解质的电化学性能研究

Electrochemical performance of MLPB-PEG400/LiCIO4 solid polymer electrolyte

赵鸽 1王金伟 1刘建1

作者信息

  • 1. 北京科技大学新材料技术研究院,北京100083
  • 折叠

摘要

Abstract

MLPB-PEG400/LiC1O4 solid polymer electrolytes were prepared by solvent casting, with the maleic anhydride polybutadiene (MLPB) grafted polyethylene glycol 400 (PEG400) as matrix and LiClO4 as alkali metal salt. The electrochemical performance of the MLPB-PEG400/LiC104 electrolytes was studied. The results show that: the MLPB-PEG400/LiC1O4 electrolyte with the mole ratio of oxide to lithium equaling to 8 shows good performance; The changes in its conductivity versus temperature obey the Arrhenius equation in a range of 25 ℃ to 90 ℃, while become insignificant when the temperature is above 100 °C; Moreover, its electrochemical stability window reaches 4.5 V.

关键词

固体聚合物电解质/聚丁二烯/电导率/电化学稳定窗口

Key words

solid polymer electrolyte/ polybutadiene/ conductivity/ electrochemical stability window

分类

信息技术与安全科学

引用本文复制引用

赵鸽,王金伟,刘建..MLPB-PEG400/LiClO4固体聚合物电解质的电化学性能研究[J].电子元件与材料,2011,30(9):36-39,4.

基金项目

北京市重点实验室基金资助项目(No.SYS100080419) (No.SYS100080419)

电子元件与材料

OA北大核心CSCDCSTPCD

1001-2028

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