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二乙烯三胺基纤维素的合成及对胆红素的吸附性能

都馨遥 方桂珍 李宏振

食品工业科技Issue(11):75-78,4.
食品工业科技Issue(11):75-78,4.

二乙烯三胺基纤维素的合成及对胆红素的吸附性能

Synthesis of diethylenetriamine cellulose and its adsorption property for bilirubin

都馨遥 1方桂珍 1李宏振1

作者信息

  • 1. 东北林业大学材料科学与工程学院,黑龙江哈尔滨150040
  • 折叠

摘要

Abstract

The new type of functional polymer adsorption material of diethylenetriamine cellulose(DETA/MCC)based on modified cellulose was synthesized with thionyl chloride and by subsequent chemical modification of the hydroxy on C6 in 2,3-diformyloxycellulose with diethylenetriamine.The corresponding product was characterized by infrared spectrum,XRD,element analyzer and its adsorption capacity of bilirubin.Experimental results showed that the aldehyde group content of oxycellulose was 81.02% and nitrogen concentrations in diethylenetriamine cellulose was 15.22%.FTIR spectra represented that diethylenetriamine was grafted on the cellulose.The crystalsize of diethylenetriamine cellulose was 58.29%,which was lower than MCC by comparison of XRD.The adsorption test of diethylenetriamine cellulose was carried in phosphate buffer.When the dynamic adsorbing balance was achieved in 2 hours,the adsorbing capacity for 0.1g/L bilirubin was 8.44mg/g at 37℃ and pH 7.4.

关键词

纤维素/二乙烯三胺/胆红素/吸附剂

Key words

cellulose/diethylenetriamine/bilirubin/adsorbent

分类

轻工纺织

引用本文复制引用

都馨遥,方桂珍,李宏振..二乙烯三胺基纤维素的合成及对胆红素的吸附性能[J].食品工业科技,2011,(11):75-78,4.

基金项目

高等学校博士学科点专项科研基金资助项目 ()

东北林业大学研究生论文资助项目 ()

食品工业科技

OA北大核心CSCDCSTPCD

1002-0306

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