食品科学2011，Vol.32Issue(18)：246-248,3.
衍生电化学法测定橘皮中的咪酰胺
Electrochemical Determination of Prochloraz in Orange Peel after Derivatization
摘要
Abstract
A method to determine prochloraz in orange peel by electrochemistry analysis after derivatization was developed.Prochloraz was stepwise extracted by acetone and ethyl acetate,and hydrolyzed into electrochemical active 2,4,6-trichlorophenol by pyridine hydrochloride.Differential pulse stripping voltammetry（DPSV） was utilized to determine prochloraz under the optimized conditions pH 4.0 and accumulation at 0 V potential for 300 s.The results showed that oxidative peak current of 2,4,6-trichlorophenol was positively linearly correlated with its concentration within the range of 9.0 × 10-9-8.0 × 10-5 mol/L.The detection limit was 9.7 × 10-10 mol/L,and the recovery between 98.5% and 113.0%.关键词
衍生/电化学/咪酰胺/橘皮Key words
derivatization/electrochemistry/prochloraz/orange peel分类
化学化工引用本文复制引用
李静,李红波,胡效亚..衍生电化学法测定橘皮中的咪酰胺[J].食品科学,2011,32(18):246-248,3.基金项目
国家自然科学基金面上基金项目 （）
盐城工学院自然科学基金项目 （）
