食品科学2012，Vol.33Issue(8)：188-190,3.
固相萃取-反相高效液相色谱法测定红毛丹中抑霉唑的残留动态
Residue Dynamic Analysis of Imazalil in Rambutan by RP-HPLC with Solid-Phase Extraction
摘要
Abstract
A reversed-phase high performance liquid chromatographic method with solid-phase extraction was proposed for the residue dynamic analysis of imazalil in rambutan.The analyte was separated on a Shim-pack VP-ODS（150 mm × 4.6 mm,5μm） using a mobile phased composed of a mixture at a volume ratio of 75：25 of methanol and acidic Na2H2PO4 solution approximately at pH 5（adjusted with 85% phosphoric acid） at a flow rate of 0.85 mL/min,and detected at 229 nm.The injection amount was 20 μL.An excellent linearity of imazalil in the range of 15.0-960.0 μg/L was achieved（r =0.9994）.The detection limit was 5.0 μg/L.The average spike recovery rates were in the range of 86.4%-104.5% with relative standard deviation of 0.84%-2.87%.The method was fast,simple,and applicable for the determination of imazalil residue in rambutan.关键词
抑霉唑/固相萃取/反相高效液相色谱/红毛丹Key words
imazalil/solid-phase extraction/RP-HPLC/rambutan分类
化学化工引用本文复制引用
高智席,江忠远,李新发,吴艳红,牟青松,敖克厚,邓传跃..固相萃取-反相高效液相色谱法测定红毛丹中抑霉唑的残留动态[J].食品科学,2012,33(8):188-190,3.基金项目
贵州省遵义市科技局项目 （）
贵州省教育厅自然科学基金项目 （）
