电子元件与材料2012,Vol.31Issue(7):15-18,4.
碳点离子液体复合物的制备及其在超级电容器中的应用
Synthesis of carbon nanoparticle ionic liquid hybrids and the application in supercapacitor
摘要
Abstract
A new carbon nanoparticle ionic liquid hybrid (CNP1L) was synthesized from ionic liquid 1-ethyl-3-methylimidazolium tetrafluoroborate and fructose by a facile one-step microwave synthetic method. Adding the CNPIL as conductive agent and binder, a new carbon based supercapacitor was prepared and compared with the traditional carbon based supercapacitor. The results show that spherical carbon nanoparticles with diameter below 4 nm exist in CNPIL. The CNPIL shows the high conductivity of 13.26× 10-3 S · cm-1 at 70 ℃. The charge-discharge efficiency of prepared supercapecitors improves from 89.1% to 97.3%. The specific capacitance reaches 251.1 F · g-1 from 115.7 F· g-1. The internal resistance has fallen from 1.95Ω of traditional carbon supercapacitor to 1.23 Ω of new carbon based supercapacitor. In addition, the cycle ability of new carbon based supercapacitor increase significantly.关键词
超级电容器/碳点离子液体/微波合成法/电化学性能Key words
supercapacitor/ carbon nanoparticle ionic liquid/ microwave synthetic method/ electrochemical property分类
信息技术与安全科学引用本文复制引用
张庆国,石丽敏,王双龙,蔡克迪,金振兴..碳点离子液体复合物的制备及其在超级电容器中的应用[J].电子元件与材料,2012,31(7):15-18,4.基金项目
国家自然科学基金资助项目(No.21003081) (No.21003081)
辽宁省教育厅重点实验资助项目(No.2009S003 ()
No.LS201001) ()