食品科学2012，Vol.33Issue(12)：119-122,4.
铜氨法生产叶绿素铜钠盐工艺优化
Optimization of Synthesis of Sodium Copper Chlorophyllin by Alkaline Cuprammonium Replacement
摘要
Abstract
Chlorophyll copper sodium salt as a non-toxic water soluble chlorophyll derivative has excellent stability and colorability and is widely used as a food additive. In the present study, the traditional preparation process for sodium copper chlorophyllin from silkworm excrement chlorophyll was modified to develop a semi-synthesis method based on alkaline cuprammonium replacement. Four reaction conditions such as ethanol concentration, pH, reaction temperature and copper amount were chosen for synthesis process optimization based on orthogonal array design using SAS statistical software. The optimal copper amount, ethanol concentration, reaction temperature and pH were 2.5 times higher than the theoretic value, 75%, 55℃, and 11.5, respectively. Under these conditions, the ethanol consumption for copper replacement was reduced by 10%, and the quality of the product obtained was in accordance with the national standard of food additives.关键词
蚕沙/铜氨法/叶绿素铜钠盐/工艺条件/SAS统计Key words
silkworm excrement/cuprammonium method/sodium copper chlorophyllin/process conditions/SASstatistical software分类
轻工纺织引用本文复制引用
喻薇,纪平雄..铜氨法生产叶绿素铜钠盐工艺优化[J].食品科学,2012,33(12):119-122,4.基金项目
华南农业大学“211工程”三期重点建设项目 （）
