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Au/γ-Al_2O_3催化氧化葡萄糖制备葡萄糖酸钠的研究

许立信 王豹 李培杰 徐艳艳 崔平

食品工业科技2012,Vol.33Issue(16):289-291,295,4.
食品工业科技2012,Vol.33Issue(16):289-291,295,4.

Au/γ-Al_2O_3催化氧化葡萄糖制备葡萄糖酸钠的研究

Catalytic oxidation of glucose to sodium gluconate by Au/γ-Al2O3 catalysts

许立信 1王豹 1李培杰 1徐艳艳 1崔平1

作者信息

  • 1. 安徽工业大学化学与化工学院,安徽马鞍山243002
  • 折叠

摘要

Abstract

Au/γ-Al2o3 catalysts were prepared by the direct anion exchange (DAE) method,characterized by TEM and XRD techniques and their catalytic performances were evaluated in glucose oxidation. The experimental results showed that as the gold Ioadings, pH and calcination temperatures increased,the catalytic activities of Au/γ-Al2o3 firstly increased and then decreased in the end. The optimal condition of catalyst preparation was as follows: HAuCI4 concentration 0.5mmol/L,pH4,calcination at 300℃ for 4h. A catalytic activity of 0.366molglu(min.gAu) were obtained over Au/γ-Al2O3 catalyst under the optimal preparation condition.

关键词

金催化剂/葡萄糖氧化/氧化铝/制备条件

Key words

gold catalyst/glucose oxidation/alumina/preparation condition

分类

轻工纺织

引用本文复制引用

许立信,王豹,李培杰,徐艳艳,崔平..Au/γ-Al_2O_3催化氧化葡萄糖制备葡萄糖酸钠的研究[J].食品工业科技,2012,33(16):289-291,295,4.

基金项目

安徽省教育厅重点项目 ()

安徽工业大学创新团队建设计划、研究生创新研究基金项目 ()

研究生导师创新基金项目 ()

食品工业科技

OA北大核心CSCDCSTPCD

1002-0306

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