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苏丹红I在纳米WO3修饰电极上的伏安行为及测定

瞿万云 胡卫兵 朱杰

食品科学2012,Vol.33Issue(14):125-128,4.
食品科学2012,Vol.33Issue(14):125-128,4.

苏丹红I在纳米WO3修饰电极上的伏安行为及测定

Voltammetric Behavior and Determination of Sudan I at Nano-WO3 Modified Carbon Paste Electrode

瞿万云 1胡卫兵 1朱杰1

作者信息

  • 1. 湖北民族学院化学与环境工程学院,湖北恩施445000
  • 折叠

摘要

Abstract

A convenient and sensitive electrochemical method was developed for the determination of Sudan I. Various experimental parameters were optimized. Nano-WO3 was synthesized by a hydrothermal method and used to modify carbon paste electrode (CPE). The voltammetric behavior of Sudan I (1-phenylzo-2-naphthalenol) was investigated by cyclic voltammetry (CV), linear sweep voltammetry (LSV) and differential pulse voltammetry (DPV). The oxidation peak current of Sudan I remarkably increased at the nano-WO3 modified electrode and linearly proportional to the concentration of Sudan I from 1.5×10^-7 to 2.0 ×10^-5 mol]L. The detection limit was 8.0×10^-8 mol/L after 2 min accumulation. The recovery rate of this method for Sudan I was in the range of 9 l. 1% -- 102%. This method is suitable for the detection of Sudan I in hot pepper products and tomato ketchup.

关键词

苏丹红染料/纳米WO3/电化学测定/食品分析

Key words

Sudan dyes/nano-W03/electrochemistry detection/food analysis

分类

化学化工

引用本文复制引用

瞿万云,胡卫兵,朱杰..苏丹红I在纳米WO3修饰电极上的伏安行为及测定[J].食品科学,2012,33(14):125-128,4.

基金项目

国家自然科学基金面上:项目 ()

湖北省教育厅优秀中青年人才项目 ()

食品科学

OA北大核心CSCDCSTPCD

1002-6630

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