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超声场中亚油酸的共轭反应

阎杰 丘泰球 杨日福 杨金兰

食品与发酵工业2012,Vol.38Issue(4):67-71,5.
食品与发酵工业2012,Vol.38Issue(4):67-71,5.

超声场中亚油酸的共轭反应

Conjugation of Linoleic Acid in Ultrasonic Field

阎杰 1丘泰球 2杨日福 3杨金兰1

作者信息

  • 1. 仲恺农业工程学院化学化工学院,广东广州510225
  • 2. 华南理工大学轻工与食品学院,广东广州510640
  • 3. 华南理工大学理学院,广东广州510640
  • 折叠

摘要

Abstract

The effects of ultrasonic intensity, ultrasonic time, temperature, usage of catalyst and reaction time on the yield of conjugated lino|eic acid were studied. The mathematic model of these factors to the yield was also estab- lished through uniform design. The product was characterized by ultraviolet spectroscopy and infrared spectroscopy. The results show that the factors of ultrasonic intensity, ultrasonic time, temperature, usage of catalyst and reaction time are all important to the yield of conjugated linoleic acid. Uniform experiments indicate that comparing with other factors, the ultrasonic intensity, in the range of 22. 17 - 27.26 W/cm2 , doesn' t play an important role in the reac- tion. Under the conditions of the experiments, the higher the temperature, the longer the reaction time and the more us- age of catalyst, will yield higher production. To obtain desirable product, the mathematic model can be used in reality to select proper parameters. In comparison with the normal method, the process assisted by ultrasound can achieve high- er yield under the same conditions; it can also reduce catalyst usage and shorten reaction time with the same yield. Spectrum analysis shows that the conjugation is reacted and the cis-trans configuration is the primary products.

关键词

亚油酸/超声/共轭反应/共轭亚油酸/数学模型

Key words

linoleic acid/ultrasound/conjugation/conjugated linoleic acid/mathematic model

分类

轻工纺织

引用本文复制引用

阎杰,丘泰球,杨日福,杨金兰..超声场中亚油酸的共轭反应[J].食品与发酵工业,2012,38(4):67-71,5.

基金项目

国家自然科学基金资助项目 ()

食品与发酵工业

OA北大核心CSCDCSTPCD

0253-990X

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