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助熔剂对Ca0.7Sr0.3MoO4∶Eu3+红色荧光粉发光性能的影响

杨旭 耿秀娟 李梓杨 陈永杰 杨英

电子元件与材料Issue(12):45-48,4.
电子元件与材料Issue(12):45-48,4.DOI:10.14106/j.cnki.1001-2028.2014.12.012

助熔剂对Ca0.7Sr0.3MoO4∶Eu3+红色荧光粉发光性能的影响

Influences of flux on luminescent properties of Ca0.7Sr0.3MoO4∶Eu3+red phosphor

杨旭 1耿秀娟 1李梓杨 1陈永杰 1杨英1

作者信息

  • 1. 沈阳化工大学 辽宁省稀土化学及应用重点实验室,辽宁 沈阳 110142
  • 折叠

摘要

Abstract

Red phosphors Ca0.7Sr0.3MoO4∶Eu3+were prepared with different fluxes (H3BO3, fluoride fluxes, mixture of H3BO3 and AlF3) by high temperature solid-phase method. The effects of fluxes on phase structure and luminescent properties of phosphors were studied by X-ray diffraction (XRD), excitation and emission spectra. The results show that, the luminescent properties of phosphors are improved by using fluxes except CaF2, and the phase structure of red phosphors is not affected. The best dosage of H3BO3 is 1%of the mass of phosphors. In these fluoride fluxes, AlF3 (dosage is 2%of the mass of phosphors) is the best for improving the luminescent properties of phosphors. H3BO3 and AlF3 added together as flux are better than the flux added independently.

关键词

白光LED/钼酸盐/红色荧光粉/高温固相法/助熔剂/发光性能

Key words

white LED/molybdate/red phosphor/high temperature solid-phase method/flux/luminescent properties

分类

数理科学

引用本文复制引用

杨旭,耿秀娟,李梓杨,陈永杰,杨英..助熔剂对Ca0.7Sr0.3MoO4∶Eu3+红色荧光粉发光性能的影响[J].电子元件与材料,2014,(12):45-48,4.

基金项目

辽宁省博士科研启动基金资助项目 ()

电子元件与材料

OACSCDCSTPCD

1001-2028

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