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淀粉预处理对反相乳液法合成高吸水树脂的影响

蒋洪强 谢新玲 童强法 黄祖强 熊海武 张友金

粮油食品科技Issue(6):25-28,4.
粮油食品科技Issue(6):25-28,4.

淀粉预处理对反相乳液法合成高吸水树脂的影响

The effect of starch pretreatment on super absorbent resins prepared via inverse emulsion polymerization

蒋洪强 1谢新玲 1童强法 1黄祖强 1熊海武 1张友金1

作者信息

  • 1. 广西大学 化学化工学院,广西石化资源加工过程强化技术重点实验室,广西 南宁 530004
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摘要

Abstract

The supper absorbent resin of starch grafting acrylic acid was prepared by inverse emulsion pol-ymerization with heating gelatinized cassava starch or mechanical activated cassava starch and acrylic acid (AA)as the raw material.The effects of mass ratio of AA to starch,concentration of initiator (APS) and crosslinking agent (MBIS)on absorbency of the resins were investigated.The functional groups of the resins were characterized by FT -IR.The results showed that the acrylate monomer was successfully grafted onto starch,and the mass ratio of AA to starch,concentration of initiator and crosslinking agent were the major factors which affected the absorbency of resin.Compared with the heat gelatinized starch graft super absorbent,mechanical activated starch grafted acrylate super absorbent had a higher maximum absorption rate of deionized water 194.51 g/g,which improved 43.14%,and a higher maximum absorp-tion rate of normal saline 16.88 g/g,which improved 27.1% Compared with the heat gelatinized pre-treatment technology,the mechanical activation pretreatment technology for preparing starch -based super absorbent resin via inverse emulsion would reduce the consumption of resources and the cost.

关键词

热糊化/机械活化/反相乳液聚合/木薯淀粉/高吸水树脂

Key words

heating gelatinized/mechanical activation/inverse emulsion polymerization/cassava starch/super absorbent resin

分类

轻工纺织

引用本文复制引用

蒋洪强,谢新玲,童强法,黄祖强,熊海武,张友金..淀粉预处理对反相乳液法合成高吸水树脂的影响[J].粮油食品科技,2015,(6):25-28,4.

基金项目

广西自然科学基金项目(2015GXNSFAA139021);广西高校科学技术研究项目(KY20152D005);广西石化资源加工及过程强化技术重点实验室主任课题基金资助 ()

粮油食品科技

1007-7561

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