中国食品学报2016，Vol.16Issue(5)：196-204,9.DOI:10.16429/j.1009-7848.2016.05.028
GC-MS/SIM内标法定量分析两种类型酒中的3-甲硫基丙醇
Analysis of 3-Methylthiopropanol in 2 Types of Liquor by Internal Standard Method with GC-MS/SIM
摘要
Abstract
3-methylthiopropanol in 2 types of liquor was quantified by internal standard method followed by Gas Chromatography-Mass Spectrum with Selected Ion Monitor (GC-MS/SIM) which was reported in this paper.4-methylth-iobutanol was used as an internal standard.The liquor was extracted by dichloromethane for sample pretreatment.The chromatographic condition carried out that:weak polar chromatographic column TG-5MS (30 m × 0.25 mm× 0.25 m),programmed temperature,inlet temperature 250 ℃.The conditions of GC-MS were optimized,and the selected ions were m/z 106 and 61.The results showed:the method had good linearity (R2=0.9991)in the range of 10 μg/L ～ 10 mg/L,the LOD was 5 μg/L,the LOQ was 10 μg/L,the recovery rate was between 86.0％ ～ 93.7％ under the level of 100 μg/L,500 μg/L and 2 mg/L,the precision were all less than 4％.14 samples from 2 types of liquor were detected.3-methylthiopropanol were detected in 4 out of 7 chixiang flavor Chinese Baijiu samples,the content were between 10.4 ～105.5 μg/L.7 fruit wine samples were detected,the content of 3-methylthiopropanol in all but one were between 10.1μg/L ～ 1.4713 mg/L.关键词
3-甲硫基丙醇/豉香型白酒/果酒/内标法Key words
3-methyhhiopropanol/chixiang flavor Chinese Baijiu/fruit wine/internal standard method引用本文复制引用
赵东瑞,柳金龙,张锋国,孙金沅,孙啸涛,黄明泉,郑福平,孙宝国..GC-MS/SIM内标法定量分析两种类型酒中的3-甲硫基丙醇[J].中国食品学报,2016,16(5):196-204,9.基金项目
国家自然科学基金-青年科学基金项目(31301466) （31301466）
北京市教委科技计划重点项目(KZ201410011015) （KZ201410011015）
