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1-3型高介电聚合物基复合材料的制备与性能

郑斌 宋宇 赵祖珍

电子元件与材料2017,Vol.36Issue(2):14-18,24,6.
电子元件与材料2017,Vol.36Issue(2):14-18,24,6.DOI:10.14106/j.cnki.1001-2028.2017.02.004

1-3型高介电聚合物基复合材料的制备与性能

Preparation and properties of 1-3 typehighdielectric polymer-based composites

郑斌 1宋宇 1赵祖珍1

作者信息

  • 1. 深圳清华大学研究院 新材料与生物医药研究所先进储能材料及器件实验室,广东 深圳 518057
  • 折叠

摘要

Abstract

Generally, ceramic materialswithhigh dielectric constant are added into polymer matrix toimprovethe dielectric propertiesof composites. One-dimensionalPLZT nanofibers, prepared by electrospinning and then coated by dopamine, were added into PVDF matrix, forming 1-3 type composites (Dopa@PLZTs-PVDF). The SEMresults show a good combination of PLZTs and PVDF matrix. Therelativedielectric constant is 14 at 100 Hz for 8.6%(volume fraction) samples, 65% higher than that of PVDF matrix. The maximal energy density is 0.4 J/cm3for 1.7%(volume fraction) samples, 10% higher than that of PVDF matrix. Proper content of PLZTs contributes to composite flexibility and cost reduction. The results demonstrate that one-dimensionalceramic fillers with low content, can enhance the dielectric constant of composites obviously.

关键词

高介电/储能密度/复合材料/纳米纤维/表面改性/静电纺丝

Key words

high dielectric constant/energy density/composite/nanofiber/surface modification/electrospinning

分类

通用工业技术

引用本文复制引用

郑斌,宋宇,赵祖珍..1-3型高介电聚合物基复合材料的制备与性能[J].电子元件与材料,2017,36(2):14-18,24,6.

基金项目

深圳市战略性新兴产业发展专项资金资助 ()

电子元件与材料

OA北大核心CSCDCSTPCD

1001-2028

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