轻工学报2017，Vol.32Issue(1)：72-81,10.DOI:10.3969/j.issn.2096-1553.2017.1.011
金属催化腈水解反应制备伯酰胺衍生物的研究进展
Research progress of hydrdysis reaction of nitriles to form amide derivatives catalyzed by metal catalyst
摘要
Abstract
Considering the high atom economy and selectivity towards hydrolysis reaction derivatives of nitriles to form amides,progress in recent years for this transformation catalyzed by different metal catalysts was reviewed such as a variety of catalysts composed of transition-metal complexes such as Mo,Ru,Rh,Pd and Au/Ag.Specially,Ru-metal catalysts was exploited deeply and draw more attention of science researcher. However,hydrolysis reaction derivatives of nitriles to form amides catalyzed by metal catalysts remains a formi-dable challenge,including the development of heterogeneous Ru-metal catalysts and high selectivity catalysts, bringing insight into the mechanism of homogeneous and heterogeneous catalytic reaction,seeking for new sys-tem with pure water as solvent.关键词
金属催化剂/腈水解反应/伯酰胺衍生物Key words
metal catalyst/hydrdy-sis reaction of nitriles/amide derivative分类
化学化工引用本文复制引用
徐粉,康位粉,孟彦羽,张立朝,方少明..金属催化腈水解反应制备伯酰胺衍生物的研究进展[J].轻工学报,2017,32(1):72-81,10.基金项目
河南省高等学校重点项目（17A150053）；郑州轻工业学院博士基金项目 （）
