轻工学报2017，Vol.32Issue(4)：1-7,7.DOI:10.3969/j.issn.2096-1553.2017.4.001
PVP络合剂对Pt/Gr催化甲醇氧化性能的影响
Effects of PVP on catalytic performance of Pt/Gr catalysts for methanol oxidation
摘要
Abstract
Pt/Gr catalysts were prepared by organic-sol method with polyvinylpyrrolidone (PVP) as complexing agent.The catalysts were characterized by FT-IR, XRD and TEM, and the electrocatalytic performances of the catalysts for methanol oxidation in acid solution were measured.The results showed that the addition of appropriate amount of PVP could greatly improve the dispersion of Pt nanoparticles of Pt/Gr catalysts and reduce the particle size.The electrocatalytic performance and stability of Pt/Gr for methanol oxidation increased with the PVP contents firstly, and then decreased.When the maximum electrocatalytic activity (current density 0.53 A/mgPt) was reached,it was 2.4 times higher than that of Pt/Gr prepared without PVP,and Pt/Gr had higher stability at PVP content=10 mg.关键词
聚乙烯吡咯烷酮/Pt/石墨烯/甲醇氧化Key words
PVP/Pt/Graphene/methanol oxidation分类
化学化工引用本文复制引用
高海丽,梁会会,林静,海瑞瑜,韩明雨..PVP络合剂对Pt/Gr催化甲醇氧化性能的影响[J].轻工学报,2017,32(4):1-7,7.基金项目
国家自然科学基金项目(U1404201) （U1404201）
郑州轻工业学院校级青年骨干教师培养对象资助计划项目(2013XGGJS007) （2013XGGJS007）
河南省高校科技创新团队支持计划项目(16IRTSTHN016) （16IRTSTHN016）
郑州轻工业学院研究生科技创新基金项目(2015002) （2015002）
郑州轻工业学院大学生创新实验项目(2016152) （2016152）
