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芥子酸模拟体系化学氧化褐变反应

董霞 王芳 庞美霞 徐令怡 崔宇倩 綦菁华

食品工业科技Issue(13):69-73,5.
食品工业科技Issue(13):69-73,5.DOI:10.13386/j.issn1002-0306.2017.13.013

芥子酸模拟体系化学氧化褐变反应

Chemical oxidative phenolic browning reactions in a sinapic acid model system

董霞 1王芳 1庞美霞 1徐令怡 1崔宇倩 1綦菁华1

作者信息

  • 1. 北京农学院食品科学与工程学院/北京农学院农产品有害微生物及农残安全检测与控制北京市重点实验室,北京102206
  • 折叠

摘要

Abstract

In order to determine the influence factor of sinapic acid chemical oxidation,so as to provide the basis for better control of fruits and vegetables browning,sinapic acid chemical oxidation simulation system was established.The sinapic acid concentration and browning degree were investigated at 315 nm and 420 nm by ultraviolet visible spectrophotometer.Chemical oxidation of sinapic acid accords with First order reaction kinetics model by kinetic fitting.The rate of chemical oxidation of sinapic acid was maximum at pH10.0 (5.38 h-1).The results of orthogonal test showed that the effect of temperature at 0.05 level on the chemical oxidative browning of sinapinic acid was significant and the effect of pH at 0.1 level on the chemical oxidative browning of sinapic acid was significant.The effect of concentration of sinapic acid at 0.1 level on the chemical oxidative browning of sinapic acid was not significant.Sinapic acid was more prone to chemical oxidation at piH10.0 than pH3.7 and pH7.0 and at 90 ℃ than 40 ℃ and 25 ℃.Sinapic acid is more susceptible to oxidative browning in high temperature and alkaline environment.For this feature,in order to as far as possible to avoid the occurrence of browning of fruits and vegetables,high temperature and alkali processing operations should be avoided.

关键词

芥子酸/化学氧化/褐变/一级反应动力学

Key words

sinapic acid/chemical oxidation/browning/first order reaction kinetics model

分类

轻工纺织

引用本文复制引用

董霞,王芳,庞美霞,徐令怡,崔宇倩,綦菁华..芥子酸模拟体系化学氧化褐变反应[J].食品工业科技,2017,(13):69-73,5.

基金项目

本研究由“现代农业产业技术体系北京市创新团队”提供资金与技术支持. ()

食品工业科技

OA北大核心CSCDCSTPCD

1002-0306

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