食品科学2017，Vol.38Issue(19)：1-6,6.DOI:10.7506/spkx1002-6630-201719001
单糖与氯化钠模型反应中3-氯-1,2-丙二醇的形成
Formation of 3-Monochloropropane-l,2-diol in Thermal Reaction Model Systems Consisting of Monosaccharides and Sodium Chloride
摘要
Abstract
The formation of 3-monochloropropane-1,2-diol (3-MCPD) was investigated in thermal reaction model systems consisting of one of six monosaccharides,sodium chloride and deionized water.Temperature had the most significant influence on 3-MCPD formation from the "glucose + sodium chloride" model system,followed by sodium chloride concentration,reaction time and glucose concentration.In addition,3-MCPD could be formed from all six monosaccharides.The highest amount (30.604 μg/kg) of 3-MCPD was formed from the "ribose + sodium chloride" model system and the lowest amount (2.498 6 μg/kg) from the "fructose + sodium chloride" model system under the same reaction conditions.5-Hydroxymethyl furfural was the most abundant volatile compound detected from the "glucose + sodium chloride" model system,followed by furfural and 2,5-dimethyl acetyl furan.According to these results and the literature,the formation mechanism of 3-MCPD was discussed herein,and 3-epoxy-1-propanol (glycidol) was suggested to be as the key intermediate.关键词
单糖/3-氯-1,2-丙二醇/热反应模型/形成机理/缩水甘油Key words
monosaccharides/3-monochloropropane-1,2-diol/thermal reaction model/formation mechanism/glycidol分类
轻工纺织引用本文复制引用
黄明泉,李娟,邹青青,孙宝国,田红玉,张玉玉..单糖与氯化钠模型反应中3-氯-1,2-丙二醇的形成[J].食品科学,2017,38(19):1-6,6.基金项目
国家自然科学基金面上项目(31471665) （31471665）
北京市属高等学校高层次人才引进与培养计划项目(CIT&TCD201404034) （CIT&TCD201404034）
