轻工学报2018,Vol.33Issue(2):13-19,7.DOI:10.3969/j.issn.2096-1553.2018.02.003
铀尾矿基多孔陶粒对对苯二酚的吸附能力研究
Study on adsorption capacity of uranium tailings-based porous ceramisite for hydroquinone
摘要
Abstract
Taking uranium tailings treated to hazard-free as the main raw material,a new type of environment fuctional material-uranium tailings-based porous ceramisite was prepared.The adsorption capacity of uranium tailings porous ceramisite for hydroquinone were investigated.The results indicated that,the removal rate and adsorption capacity of uranium tailings-based porous ceramisite for hydroquinone uranium tailings were 91.2%and 4.56 mg/g respectively with a pH value of 7.During the adsorption of the uranium tailing-based porous ceramsite for hydroquinone,the liquid film diffusion dominated and was more accurately described by the pseu-do-first-order kinetic equation.Data fitting degree of Langmuir equation and Koble-Corrigan equation of adsorp-tion isotherm was higher.The adsorption properties of uranium tailings-based porous ceramsite were fixed at a fixed site by a single layer molecular layer,and it was a non-uniform composite adsorption system.The adsorp-tion process of uranium tailings porous ceramisite for hydroquinone was a high fitting for the liquid film diffu-sion model.The R2and k value were 0.847 8 and 0.041 7 respectively.关键词
铀尾矿基多孔陶粒/对苯二酚/吸附动力学模型/吸附热力学模型/动边界模型Key words
uranium tailings-based porous ceramisite/hydroquinone/adsorption kinetics model/adsorption thermodynamics model/dynamic boundary model分类
化学化工引用本文复制引用
吴照洋,谷一鸣,何宇,丁洲乐,师梓宸,李梦雨,高如琴..铀尾矿基多孔陶粒对对苯二酚的吸附能力研究[J].轻工学报,2018,33(2):13-19,7.基金项目
中国地质调查局地质矿产评价专项项目(YMZB -2017014F) (YMZB -2017014F)
华北水利水电大学大学生科技创新项目(2017XB086) (2017XB086)