电子元件与材料2018，Vol.37Issue(5)：106-110,5.DOI:10.14106/j.cnki.1001-2028.2018.05.019
低温固相法制备亚微米级钛酸钡粉体的研究
Preparation of submicron barium titanate powders by solid state reaction at low temperature
摘要
Abstract
Barium titanate is widely used in electronic components such as multilayer ceramic capacitors(MLCC) due to its excellent electrical properties. The powders traditional preparation process of high energy consumption and wastewater problems can not be effectively resolved. Submicron BaTiO3powders with uniform spherical morphology were synthesized by solid state reaction at low temperature, in which, barium hydroxide octahydrate(Ba(OH)2·8H2O) and meta-titanic acid (H2TiO3) were used as the raw materials. Then the effects of ball milling process(grinding speed, grinding time) and synthetic process(reaction temperature, reaction time) on the properties of barium titanate were studied. The crytal phase composition, morphology and particle size of the product were characterized by X-ray diffraction(XRD) and field emission scanning electron microscopy(SEM). The results show that the cubic phase barium titanate with high crystallinity and uniform particle size can be obtained when the raw materials are ground at 700 r/min for 5 h and then kept at 100 ℃ for 3 h.关键词
钛酸钡/固相法/低温/亚微米级/偏钛酸/无机功能粉体Key words
barium titanate/solid state reaction/low temperature/submicron/meta-titanic acid/inorganic functional powder分类
化学化工引用本文复制引用
丁厚远,商少明,赵贝贝,秦高敏,刘浩..低温固相法制备亚微米级钛酸钡粉体的研究[J].电子元件与材料,2018,37(5):106-110,5.基金项目
贵州省科学与技术重大项目资助(20126016) （20126016）
