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负载S-g-C3N4/MgAl-CLDH光催化砂浆的去污及水化性能研究

林淑瑾 罗盛洋 熊晓立

硅酸盐通报2024,Vol.43Issue(1):44-51,8.
硅酸盐通报2024,Vol.43Issue(1):44-51,8.

负载S-g-C3N4/MgAl-CLDH光催化砂浆的去污及水化性能研究

Decontamination and Hydration Performance of Photocatalytic Mortar Loaded with S-g-C3N4/MgAl-CLDH

林淑瑾 1罗盛洋 2熊晓立2

作者信息

  • 1. 福州市建设工程质量监督站,福州 350007
  • 2. 福州大学土木工程学院,福州 350108
  • 折叠

摘要

Abstract

In this study,a new type of photocatalytic composite material"sulfur-doped carbon nitride/calcined magnesium aluminum hydrotalcite(S-g-C3N4/MgAl-CLDH)"was synthesized and loaded on cement mortar through internal doping.The nitrogen oxide(NOx)degradation and hydration performance of photocatalytic mortar were tested.The results show that when the photocatalyst dosage is less than 5%(mass fraction),the S-g-C3N4/MgAl-CLDH content is directly proportional to the NOx degradation rate of mortar.When the photocatalyst dosage exceeds 5%,the NOx degradation performance of mortar begins to decrease due to agglomeration.In addition,due to the nucleation effect of nanomaterials,the incorporation of an appropriate amount of S-g-C3N4/MgAl-CLDH significantly improves the early(1 d)hydration degree of cement.However,due to its water absorption and agglomeration phenomenon,excess S-g-C3N4/MgAl-CLDH reduces the later hydration degree of cement.When the photocatalyst dosage is 7%,the 28 d strength of cement mortar significantly decreases compared with the control mortar.In addition,an appropriate amount of S-g-C3N4/MgAl-CLDH(3%)can improve 28 d strength of mortar due to its micro-filling effect.

关键词

光催化砂浆/g-C3N4/MgAl-CLDH/氮氧化物降解/抗压强度/水泥水化

Key words

photocatalytic mortar/g-C3N4/MgAl-CLDH/nitrogen oxide degradation/compressive strength/cement hydration

分类

化学化工

引用本文复制引用

林淑瑾,罗盛洋,熊晓立..负载S-g-C3N4/MgAl-CLDH光催化砂浆的去污及水化性能研究[J].硅酸盐通报,2024,43(1):44-51,8.

硅酸盐通报

OA北大核心CSTPCD

1001-1625

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