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钢渣粉对提钛渣胶凝材料中氯离子固化效果的影响机理研究OA

Mechanism study on the effect of steel slag powder on the chlorine ion curing effect in titanium extraction slag cementitious materials

中文摘要英文摘要

钢渣粉(SSP)用作掺料可以促进胶凝材料的强度增长,但其对胶凝材料中 Cl-固化效果的影响机理尚不明确.基于此,将磨细的SSP加入到提钛渣(TETS)中,制备了CaO-SSP-TETS胶凝材料固化体,探究钢渣粉对固化体中Cl-固化效果的影响机理.保持CaO含量和液固比不变,考查不同钢渣粉与提钛渣质量比、不同养护龄期固化体中Cl-的固化量及固化量增长倍数,采用氯离子快速测定仪、XRD、SEM和 EDS分别对固化体浸出液的 Cl-浓度、水化反应产物、微观形貌和微区成分进行表征,结果表明:Cl-固化量与提钛渣掺量成正比,Cl-固化量增长倍数随钢渣粉掺量的升高先增大后减小,钢渣粉与提钛渣的质量比为 1∶1 时,Cl-固化量的增长倍数最高.固化体中新生成物相主要是水铝钙石、方解石和水化硅酸钙,固化体对 Cl-的固化主要是水铝钙石对 Cl-的化学固化和水化硅酸钙对Cl-的物理吸附.

The use of steel slag powder(SSP)as an admixture can promote the strength growth of cementitious materials,but the mechanism of its influence on the Cl-curing effect in cementitious materials is not yet clear.Based on this,finely ground steel slag powder is added to titanium extraction slag(TETS)to prepare CaO-SSP-TETS cementitious material solidified body,and the influence mechanism of steel slag powder on the Cl-solidification effect in the solidified body is explored.Keeping the CaO content and liquid-solid ratio constant,different mass ratios of steel slag powder to titanium extraction slag,the solidification amount of Cl-in the solidified body at different curing ages,and the growth rate of solidification amount were investigated.The Cl-concentration,hydration reaction products,microstructure,and microstructure of the solidified body leachate were characterized using a chloride ion rapid analy-zer,XRD,SEM,and EDS,The results show that the amount of Cl-solidified is proportional to the amount of titani-um slag,and the increase multiple of Cl-solidified increases first and then decreases with the increase of steel slag content.When the mass ratio of steel slag powder to titanium extraction slag is 1∶1,the increase multiple of Cl-solidified is the highest.The newly formed phases in the solidified body are mainly gibbsite,calcite and hydrated calcium silicate.The solidification of Cl-by the solidified body is mainly chemical solidification of Cl-by gibbsite and physical adsorption of Cl-by hydrated calcium silicate.

万紫妍;唐颂;罗利明;彭耀;谢宇航;杨越;梁雨

西南科技大学 环境与资源学院,四川 绵阳 621010西南科技大学 环境与资源学院,四川 绵阳 621010||西南科技大学 矿物材料及应用研究所,四川 绵阳 621010西南科技大学 环境与资源学院,四川 绵阳 621010||西南科技大学 矿物材料及应用研究所,四川 绵阳 621010||西南科技大学 核废物与环境安全国防重点学科实验室,四川 绵阳 621010

化学工程

提钛渣钢渣粉固化体氯离子固化化学固化物理吸附

titanium extraction slagsteel slag powdersolidified bodychlorine ion curingchemical curingphysi-cal adsorption

《化工矿物与加工》 2024 (001)

28-34 / 7

四川省高校高价值专利育成中心培育项目(2022-ZS-00031);四川省省级大学生创新创业训练计划项目(S202110619113).

10.16283/j.cnki.hgkwyjg.2024.01.005

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