碱金属离子共掺Sr3Ga2Ge4O14∶Dy3+发光性能研究OACSTPCD

In this paper,a series of novel Sr3-xGa2Ge4O14∶xDy3+(x=0～0.40)(mole fraction)and Sr2.68Ga2Ge4O14∶0.16Dy3+,0.16M+(M=Li,Na,K)phosphors were prepared by high-temperature solid-phase method.EDS analysis confirms the presence of Sr,Ga,Ge,O and Dy elements in the phosphors.The series Sr3-xGa2Ge4O14∶xDy3+produce strong yellow light emission with 568 nm as the dominant wavelength under 350 nm optical excitation,corresponding to the 4F9/2→6 H13/2 transition.The emission spectra of the phosphor show that the emission intensity varies with the increase of Dy3+concentration and reaches its maximum at x=0.16.The co-doping of alkali metal M(M=Li,Na,K)as a charge compensation ion,among which Li+has the most obvious effect on increasing the emission intensity of Dy3+,led to the increase of the emission intensity of the phosphor to twice that of the phosphor in the absence of the charge compensation ion.In addition,the fluorescence lifetime of the phosphor decrease continuously with the increase of Dy3+doping concentration.Finally,the CIE chromaticity coordinates and thermal stability of the phosphor Sr2t68Ga2Ge4O14∶0.16Dy3+,0.16Li+are explored,and its CIE chromaticity coordinates are(0.371 9,0.404 6),which are located in the yellow region,and its luminescence intensity at 453 K is about 95.5％of its room temperature luminescence intensity.Therefore,Dy3+,Li+co-doped Sr3-x Ga2 Ge4 O14 phosphor is a potential candidate material for display devices and white light LED devices.