岩石矿物学杂志2024，Vol.43Issue(1)：109-116,8.DOI:10.20086/j.cnki.yskw.2024.0109
凹凸棒石-双交联水凝胶微球钝化修复镉污染土壤研究
Passivation remediation of cadmium contaminated soil by attapulgite-double-crosslinked hydrogel microspheres
摘要
Abstract
In order to study the passivation remediation effect of attapulgite-double-crosslinked hydrogel micro-spheres(SA/PVA/ATP)on cadmium contaminated soil,SA/PVA/ATP was added to cadmium contaminated soil with concentration of 3.72 mg/kg for flooding cultivation,using simulated acid rain,mixed extractant of diethyle-netriamine pentaacetic acid(DTPA)and triethanolamine(TEA)(DTPA extractant)to extract available cadmium,and using sequential extraction method of the European Community Bureau of Standards(BCR)to extract different forms of cadmium in soil.The correlation between SA/PVA/ATP addition,available cadmium and various forms of cadmium in soil was discussed.The passivation capacity,remediation efficiency and heavy metal risk assessment index were calculated,and the passivation mechanism of SA/PVA/ATP on soil cadmium was explored.The results show that with the increase of the amount of SA/PVA/ATP,the available cadmium content of DTPA extractant and acid rain extraction decrease significantly from 1.72 mg/kg and 0.024 mg/kg to 0.66 mg/kg and 0.004 4 mg/kg respectively,the content of weak acid extractable and reducible cadmium in soil decrease significantly from 1.40 mg/kg and 0.81 mg/kg to 1.01 mg/kg and 0.41 mg/kg,respectively,while the content of oxidizable and residual cadmium increase significantly from 0.86 mg/kg and 0.63 mg/kg to 0.95 mg/kg and 1.27 mg/kg,respectively.The addition of material has a significant negative correlation with available cadmium,weakly acid extractable cad-mium and reducible cadmium,while a significant positive correlation with oxidizable cadmium and residual cadmi-um.When the addition of SA/PVA/ATP is 2.0％,the maximum passivation capacity is 19.15 mg/kg,the maxi-mum remediation efficiency is 34.89％,and the soil environment fall from high risk to medium risk.SA/PVA/ATP can reduce the bioavailability of cadmium and realize the passivation remediation of cadmium contaminated soil through transforming the weak acid extracted and reducible forms into oxidizable and residual forms in soil.关键词
镉/土壤/钝化修复/凹凸棒石-双交联水凝胶/形态转化Key words
cadmium/soil/passivation remediation/attapulgite-double-crosslinked hydrogel microspheres/form transformation分类
天文与地球科学引用本文复制引用
钟晓琴,贺广喜,马雪,朱霞萍,任维,赵平..凹凸棒石-双交联水凝胶微球钝化修复镉污染土壤研究[J].岩石矿物学杂志,2024,43(1):109-116,8.基金项目
国家自然科学基金项目(42267009) （42267009）
贵州省地矿局科技计划项目(黔地矿科合[2019]1号)National Natural Science Foundation of China(42267009) （黔地矿科合[2019]1号）
Science and Technology Plan Project of Guizhou Geology and Mining Bureau(Qian Geology and Mining Science and Technology Cooperation[2019]No.1) （Qian Geology and Mining Science and Technology Cooperation[2019]No.1）
